The thermal degradation of poly(-(d)-β-hydroxybutyric acid): Part 1—Identification and quantitative analysis of products
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Uncatalytic pyrolysis performed by heating the polymer to 500 °C under vacuum or N2 leads to the formation of PHA oligomers, crotonic acid, and several volatile side products.
“While uncatalytic pyrolysis performed by heating the polymer to 500 °C under vacuum or N2 leads to the formation of PHA oligomers, crotonic acid, and several volatile side products (Scheme 22A), 465”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [465]
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References 21 · Cited by 235
- Authors
- Grassie, N., Murray, E. J., & Holmes, P. A.
- Affiliations
- University of Glasgow (GB)
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 1984-01
- Volume
- 6
- Issue
- 1
- Pages
- 47-61
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W2001468312
- Cited by
- 235
- References
- 21
- Citations by year
- 2026: 2 · 2025: 5 · 2024: 4 · 2023: 4 · 2022: 3 · 2021: 10 · 2020: 5 · 2019: 4 · 2018: 6 · 2017: 7 · 2016: 7 · 2015: 7 · 2014: 13 · 2013: 8 · 2012: 8
- FWCI
- 2.20
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Degradation and Stability (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- thermal degradation, vacuum pyrolysis, crotonic acid, β-butyrolactone, ketenes, acetaldehyde, propylene, carbon dioxide
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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