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Highly selective hydrogenation of furfural over supported Pt nanoparticles under mild conditions
Open accessAbstract
The selective liquid phase hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on SiO2, ZnO, γ-Al2O3, CeO2 is reported under extremely mild conditions. Ambient hydrogen pressure, and temperatures as low as 50 °C are shown sufficient to drive furfural hydrogenation with high conversion and >99% selectivity to furfuryl alcohol. Strong support and solvent dependencies are observed, with methanol and n-butanol proving excellent solvents for promoting high furfuryl alcohol yields over uniformly dispersed 4 nm Pt nanoparticles over MgO, CeO2 and γ-Al2O3. In contrast, non-polar solvents conferred poor furfural conversion, while ethanol favored acetal by-product formation. Furfural selective hydrogenation can be tuned through controlling the oxide support, reaction solvent and temperature.
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Cited by
Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals
Li, X., Jia, P., & Wang, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01838 · Cited by 834
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
Akinbile, B. J., Matsinha, L. C., Makhubela, B. C. E., & Ambushe, A. A. (2021) · Minerals · doi:10.3390/min11080895 · Cited by 6
Metadata
- Authors
- Taylor, M. J., Durndell, L. J., Isaacs, M. A., Parlett, C. M. A., Wilson, K., Lee, A. F., & Kyriakou, G.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2016-01
- Volume
- 180
- Pages
- 580-585
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W1822985148
- Cited by
- 397
- References
- 0
- FWCI
- 14.63
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Highly selective hydrogenation of furfural over supported Pt nanoparticles under mild conditions. https://app.cochat.ai/papers/10.1016/j.apcatb.2015.07.006
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- Taylor, M. J., Durndell, L. J., Isaacs, M. A., Parlett, C. M. A., Wilson, K., Lee, A. F., & Kyriakou, G. (2016). Highly selective hydrogenation of furfural over supported Pt nanoparticles under mild conditions. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2015.07.006
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