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Cited by 257

The DOI matches its Crossref record; 64 of the 64 references it cites were found in a registry or an index.

P25@CoAl layered double hydroxide heterojunction nanocomposites for CO2 photocatalytic reduction

Open access
Kumar, Santosh, Isaacs, Mark A., Trofimovaite, Rima, Durndell, Lee, Parlett, Christopher M.A., Douthwaite, Richard E., Coulson, Ben, Cockett, Martin C.R., Wilson, Karen, Lee, Adam F.·2017·Applied Catalysis B: Environmental

Abstract

Artificial photosynthesis driven by inorganic photocatalysts offers a promising route to renewable solar fuels, however efficient CO 2 photoreduction remains a challenge. A family of hierarchical nanocomposites, comprising P25 nanoparticles encapsulated within microporous CoAl-layered double hydroxides (CoAl-LDHs) were prepared via a one-pot hydrothermal synthesis. Heterojunction formation between the visible light absorbing CoAl-LDH and UV light absorbing P25 semiconductors extends utilisation of the solar spectrum, while the solid basicity of the CoAl-LDH increases CO 2 availability at photocatalytic surfaces. Matching of the semiconductor band structures and strong donor–acceptor coupling improves photoinduced charge carrier separation and transfer via the heterojunction. Hierarchical P25@CoAl-LDH nanocomposites exhibit good activity and selectivity (>90%) for aqueous CO 2 photoreduction to CO, without a sacrificial hole acceptor. This represents a facile and cost-effective strategy for the design and development of LDH-based nanomaterials for efficient photocatalysis for renewable solar fuel production from particularly CO 2 and water.

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Crossref · 10.1016/j.apcatb.2017.03.006

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Metadata

Authors
Kumar, S., Isaacs, M. A., Trofimovaite, R., Durndell, L., Parlett, C. M. A., Douthwaite, R. E., Coulson, B., Cockett, M. C. R., Wilson, K., & Lee, A. F.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2017-07
Volume
209
Pages
394-404
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2592489455
Cited by
257
References
64
FWCI
7.61
Type
journal article
Language
en
Open access
hybrid

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The paper
Kumar, S., Isaacs, M. A., Trofimovaite, R., Durndell, L., Parlett, C. M. A., Douthwaite, R. E., Coulson, B., Cockett, M. C. R., Wilson, K., & Lee, A. F. (2017). P25@CoAl layered double hydroxide heterojunction nanocomposites for CO2 photocatalytic reduction. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2017.03.006

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.