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Synergistic effect of Zr-MOF on phosphomolybdic acid promotes efficient oxidative desulfurization
Abstract
Abstract Synergistic effects between active metal species and carriers show vital importance to redox catalysts. For this study, a successful synthetic strategy is obtained from hybrid materials involving the combination of phosphomolybdic acid (PMA) and Zr-MOF. The electronic structures of the PMA/UiO-66 composites are elucidated by FTIR, Raman, XPS, UV–vis and NMR spectra. The results suggest that Mo5+ species are newly created on the composites due to the electron transfer from the conduction band of Zr-MOF to PMA. The formed Mo5+ species contribute to a high intrinsic oxidative desulfurization activity for the PMA/UiO-66 composites. Radical scavenger experiments and DFT calculations indicate that Mo5+ with rich electron density facilitates the generation of OH reactive species. The approach can be employed to design other transition metal composite catalysts providing d electrons with unique MOF structures for enhanced catalytic activities of the redox reactions.
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Cites
Effect of the damping function in dispersion corrected density functional theory
Grimme, S., Ehrlich, S., & Goerigk, L. (2011) · Journal of Computational Chemistry · doi:10.1002/jcc.21759 · Cited by 28,221
A fast and robust algorithm for Bader decomposition of charge density
Henkelman, G., Arnaldsson, A., & Jónsson, H. (2006) · Computational Materials Science · doi:10.1016/j.commatsci.2005.04.010 · Cited by 10,723
Cited by
Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks
Samaniyan, M., Mirzaei, M., Khajavian, R., Eshtiagh-Hosseini, H., & Streb, C. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03439 · Cited by 389
Liu, Y., Yue, C., Sun, F., Bao, W., Chen, L., Zeb, Z., Wang, C., Ma, S., Zhang, C., Sun, D., et al. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.140105 · Cited by 69
Metadata
- Authors
- Zhang, X.-M., Zhang, Z., Zhang, B., Yang, X., Chang, X., Zhou, Z., Wang, D.-H., Zhang, M.-H., & Bu, X.-H.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2019-11
- Volume
- 256
- Pages
- 117804
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W2952436226
- Cited by
- 195
- References
- 2
- FWCI
- 13.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, X.-M., Zhang, Z., Zhang, B., Yang, X., Chang, X., Zhou, Z., Wang, D.-H., Zhang, M.-H., & Bu, X.-H. (2019). Synergistic effect of Zr-MOF on phosphomolybdic acid promotes efficient oxidative desulfurization. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.117804
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