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FeNi alloys encapsulated in N-doped CNTs-tangled porous carbon fibers as highly efficient and durable bifunctional oxygen electrocatalyst for rechargeable zinc-air battery

Wang, Zhe, Ang, Jiaming, Liu, Jian, Ma, Xiu Yun Daphne, Kong, Junhua, Zhang, Youfang, Yan, Tao, Lu, Xuehong·2020·Applied Catalysis B: Environmental

Abstract

Abstract It remains a great challenge to develop high-efficient, low-cost and robustly stable bifunctional oxygen electrocatalysts for rechargeable metal-air batteries. Herein, we report a promising electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The electrocatalysts are composed of nanostructured FeNi alloy nanoparticles inlaid on N-doped carbon nanotubes (CNTs)-tangled porous carbon fibers (FeNi/N-CPCF). Benefiting from its hierarchically porous structures with bamboo-like CNTs grafted, and strong synergetic coupling between FeNi alloys and N-doped carbon species, the as-prepared FeNi/N-CPCF-950 demonstrates a half-wave potential of 0.867 V for ORR and a low operating potential of 1.585 V at 10 mA cm−2 for OER in 0.1 M KOH, outperforming commercial Pt/C and RuO2. Moreover, such bifunctioal catalyst endows the homemade zinc-air batteries with a high energy efficiency of 61.5%, small charge-discharge voltage gap of 0.764 V, and outstanding cycling performance (640 h, 960 cycles) at 10 mA cm−2 under ambient conditions.

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Metadata

Authors
Wang, Z., Ang, J., Liu, J., Ma, X. Y. D., Kong, J., Zhang, Y., Yan, T., & Lu, X.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2020-04
Volume
263
Pages
118344
ISSN
0926-3373 (ISSN-L)
OpenAlex
W2982955030
Cited by
293
References
4
FWCI
7.73
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: FeNi alloys encapsulated in N-doped CNTs-tangled porous carbon fibers as highly efficient and durable bifunctional oxygen electrocatalyst for rechargeable zinc-air battery. https://app.cochat.ai/papers/10.1016/j.apcatb.2019.118344
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Wang, Z., Ang, J., Liu, J., Ma, X. Y. D., Kong, J., Zhang, Y., Yan, T., & Lu, X. (2020). FeNi alloys encapsulated in N-doped CNTs-tangled porous carbon fibers as highly efficient and durable bifunctional oxygen electrocatalyst for rechargeable zinc-air battery. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2019.118344

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