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Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane
Open accessAbstract
Abstract Ni-based mesoporous mixed CeO2-Al2O3 oxide catalysts prepared by one pot Evaporation Induced Self Assembly (EISA) were tested in dry reforming of methane. The textural, structural and physicochemical properties of the catalysts were studied by N2 adsorption-desorption, TEM-EDS, XRD and elemental analysis. The mobility of oxygen in the structure and the redox properties were investigated by OSCC measurements, TPR and in situ DRIFTS. Finally, the post-reaction samples were analyzed by TGA, RAMAN and TEM. The calcined catalysts prepared by EISA method present mesoporous structures with highly dispersed Ni in the form of NiAl2O4 spinel clusters. After reduction, small size metallic Ni particles are observed (
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Fundamentals of Mesostructuring Through Evaporation‐Induced Self‐Assembly
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Metadata
- Authors
- Marinho, A. L. A., Toniolo, F. S., Noronha, F. B., Epron, F., Duprez, D., & Bion, N.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2021-02
- Volume
- 281
- Pages
- 119459
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W3081273442
- Cited by
- 257
- References
- 38
- FWCI
- 6.48
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Marinho, A. L. A., Toniolo, F. S., Noronha, F. B., Epron, F., Duprez, D., & Bion, N. (2021). Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119459
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