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Nitrogen doped g-C3N4 with the extremely narrow band gap for excellent photocatalytic activities under visible light
Abstract
Abstract In this work, nitrogen doping g-C3N4 (NCN) with the extremely narrow band gap was prepared and applied for the photodegradation of phenols. Experiments and DFT (Density functional theory) computation identified that N-doping introduced in the g-C3N4 matrix by substituting C atoms. DFT, PL (Photoluminescence) spectra, optical property characteristic and PEC (Photoelectrochemical) indicated that NCN possess extremely narrow band gap, efficient photogenerated carrier separation and the charge transfer, which enhanced the absorption of visible light and further promote the photocatalytic activity. As a result, NCN(2:2) showed about twice higher photodegradation efficiencies and 3 times rate constant than pristine g-C3N4. Radical trapping experimental show that •O2- radical and h+ served as crucial active species during the whole photodegradation reaction. This work provided a strategy to enhance the photocatalytic activity of photocatalysts via introduce foreign atoms in matrix.
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Cites
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
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Graphene‐Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities
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Enhanced Photoresponsive Ultrathin Graphitic-Phase C3N4Nanosheets for Bioimaging
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Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C3N4
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Cited by
Alaghmandfard, A., & Ghandi, K. (2022) · Nanomaterials · doi:10.3390/nano12020294 · Cited by 465
Liu, S., Wang, M., He, Y., Cheng, Q., Qian, T., & Yan, C. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214882 · Cited by 236
Metadata
- Authors
- Zhu, D., & Zhou, Q.
- Venue
- Applied Catalysis B: Environmental
- Publisher
- Elsevier BV
- Published
- 2021-02
- Volume
- 281
- Pages
- 119474
- ISSN
- 0926-3373 (ISSN-L)
- OpenAlex
- W3082356700
- Cited by
- 419
- References
- 46
- FWCI
- 9.78
- Type
- journal article
- Language
- en
- Open access
- closed
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