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Cited by 478

The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.

Co3O4 anchored in N, S heteroatom co-doped porous carbons for degradation of organic contaminant: role of pyridinic N-Co binding and high tolerance of chloride

Peng, Lijing, Shang, Yanan, Gao, Baoyu, Xu, Xing·2021·Applied Catalysis B: Environmental

Abstract

Abstract In this work, Co3O4 embedded nitrogen and sulfur co-doped porous char (Co3O4@NSC) was prepared after one-pot pyrolysis of N, S in-rich rubber powder (RP) to determine the binding relationship between Co nanoparticles and multiple doped heteroatoms. Results indicated pyridinic N was more easily to coordinate with Co3O4 nanoparticles, forming the pyridinic N-Co binding in Co3O4@NSC, which was the dominant catalytic sites for peroxymonosulfate (PMS) activation. Paracetamol (PCM) degradation was greatly facilitated with Cl- surrounding in Co3O4@NSC/PMS system due to the formation of large amounts of HOCl generated from the direct reaction of Cl- with PMS. The Cl↓ serving as a precursor of HOCl by reacting with PMS can be further strengthened by pyridinic N-Co bindings in Co3O4@NSC than the NSC. As a result, the pyridinic Co-N sites not only acted as the essential catalytic sites for PMS activation, but also accelerated the formation of HOCl at high level of Cl-.

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Metadata

Authors
Peng, L., Shang, Y., Gao, B., & Xu, X.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2021-03
Volume
282
Pages
119484
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3087613412
Cited by
478
References
52
FWCI
20.72
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Co3O4 anchored in N, S heteroatom co-doped porous carbons for degradation of organic contaminant: role of pyridinic N-Co binding and high tolerance of chloride. https://app.cochat.ai/papers/10.1016/j.apcatb.2020.119484
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Peng, L., Shang, Y., Gao, B., & Xu, X. (2021). Co3O4 anchored in N, S heteroatom co-doped porous carbons for degradation of organic contaminant: role of pyridinic N-Co binding and high tolerance of chloride. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119484

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