Dissolution-precipitation reactions controlling fast formation of dolomite under hydrothermal conditions
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Mg-calcite precipitating at ambient temperature is quickly dissolved at higher temperatures of 200-300 °C to form dolomite and other Mg-Ca anhydrous carbonates including protodolomite.
“Montes-Hernandez et al. [140] showed that Mg-calcite precipitating at ambient temperature (Figure 8a) is quickly dissolved at higher temperatures (200~300 °C) to form dolomite and other Mg-Ca anhydrous carbonates (including protodolomite) (Figure 8b).”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [140]
Micron-sized rhombohedrally ordered dolomite particles precipitate.
“Finally, micron-sized rhombohedrally ordered dolomite particles precipitate (Figure 8c).”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [140]
Metastable mineral phases dissolve in turn to form new dolomite particles or nourish existing dolomite particles by a crystal growth process.
“These metastable mineral phases dissolve in turn to form new dolomite particles or nourish the existing dolomite particles by a crystal growth process.”
From Thermodynamic and Kinetic Studies of Dolomite Formation: A Review (2023) · cites this paper as [140]
Cites
Dolomite: occurrence, evolution and economically important associations
Warren, J. (2000) · Earth-Science Reviews · doi:10.1016/s0012-8252(00)00022-2 · Cited by 1,435 · cited 10× · see citing works
“In these nonequilibrated systems, organic degradation can also lead to a significant increase in the carbonate alkalinity (2CH2O (organic matter) þ SO4 2 / H2S þ 2HCO3 ) of interacting fluids via bacterial and/or thermochemical sulfate reduction (e.g. Compton, 1988; Warren, 2000; Machel, 2001; Nash et al., 2011).”
BackgroundInfluentialThe dolomite problem; control of precipitation kinetics by temperature and saturation state
Arvidson, R. S. (1999) · American Journal of Science · doi:10.2475/ajs.299.4.257 · Cited by 447 · cited 3× · see citing works
“Moreover, the scanty distribution of recent dolomite in natural environments contrasts strongly with its abundance in ancient sedimentary rocks of marine origin, leading to the paradox commonly referred to as the “dolomite problem” (Compton, 1988; Arvidson and Mackenzie, 1997, 1999).”
BackgroundKrause, S., Liebetrau, V., Gorb, S., Sánchez-Román, M., McKenzie, J. A., & Treude, T. (2012) · Geology · doi:10.1130/g32923.1 · Cited by 206 · see citing works
MCKENZIE, J. A., & VASCONCELOS, C. (2009) · Sedimentology · doi:10.1111/j.1365-3091.2008.01027.x · Cited by 186 · see citing works
KENWARD, P. A., GOLDSTEIN, R. H., GONZÁLEZ, L. A., & ROBERTS, J. A. (2009) · Geobiology · doi:10.1111/j.1472-4669.2009.00210.x · Cited by 175 · see citing works
Recrystallization of dolomite: An experimental study from
Malone, M. J., Baker, P. A., & Burns, S. J. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(96)00062-2 · Cited by 122 · cited 2× · see citing works
“…is not necessarily an isovolumic process, i.e. the dissolution of primary minerals is not necessarily coupled in time and space with the precipitation of secondary minerals, as frequently assumed for dolomite formation requiring long durations (Dockal, 1988; Malone et al., 1996; Warren, 2000).”
BackgroundTentative kinetic model for dolomite precipitation rate and its application to dolomite distribution
Arvidson, R. S., & Mackenzie, F. T. (1997) · Aquatic Geochemistry · doi:10.1007/bf00119858 · Cited by 74 · see citing works
Montes-Hernandez, G., Findling, N., Renard, F., & Auzende, A.-L. (2014) · Crystal Growth & Design · doi:10.1021/cg401548a · Cited by 31 · see citing works
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Structure, genesis and resources efficiency of dolomite: New insights and remaining enigmas
Cai, W. K., Liu, J. H., Zhou, C. H., Keeling, J., & Glasmacher, U. A. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120191 · Cited by 61 · see citing works
Thermodynamic and Kinetic Studies of Dolomite Formation: A Review
Chen, C., Zhong, H., Wang, X., Ning, M., Wang, X., Ge, Y., Wang, H., Tang, R., & Hou, M. (2023) · Minerals · doi:10.3390/min13121479 · Cited by 43 · see citing works
- Authors
- Montes-Hernandez, G., Findling, N., & Renard, F.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Montes-Hernandez, German
- Venue
- Applied Geochemistry
- Publisher
- Elsevier BV
- Published
- 2016-10
- Volume
- 73
- Pages
- 169-177
- ISSN
- 0883-2927 (ISSN-L)
- OpenAlex
- W2512222923
- Cited by
- 54
- References
- 8
- Citations by year
- 2026: 7 · 2025: 6 · 2024: 4 · 2023: 4 · 2022: 10 · 2021: 7 · 2020: 9 · 2019: 2 · 2018: 3 · 2017: 2
- FWCI
- 0.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Geochemistry (publishedVersion)
- Funders
- French National Center for Scientific Research (CNRS) (ANR-11-BS56-0004)
- Université Grenoble Alpes (ANR-10-JCJC-0505)
- ANR French research agency
- Topics
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- dolomite formation, hydrothermal dolomite, dissolution-precipitation, magnesian calcite, thermal aging, magnesite, aragonite, brucite, mineral dissolution, carbonate platform, Rietveld refinement, X-ray diffraction
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