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A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols
Abstract
Biodiesel could be synthesized using Brønsted acidic ionic liquid N-methyl-2-pyrrolidonium methyl sulfonate ([NMP][CH(3)SO(3)]) as a catalyst, specially with free long-chain fatty acids or their mixtures, as well as with low-molecular weight alcohols as substrates. This catalyst showed good catalytic and reusable performance under mild conditions and without any additional organic solvent. The ionic liquid could be reused eight times after the water in the ionic liquid was removed. The yields of fatty acid alkyl esters could reach between 93.6% and 95.3% after the esterifications were carried out at 70 degrees C for 8h. Therefore, an efficient and environmentally friendly catalyst was provided for the synthesis of biodiesel from low-cost feedstocks such as waste oils.
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Cites
H. Davis, J. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1072 · Cited by 1,053
Cited by
Advancements in solid acid catalysts for biodiesel production
Su, F., & Guo, Y. (2014) · Green Chem. · doi:10.1039/c3gc42333f · Cited by 489
Ionic Liquids: Synthesis and Applications in Catalysis
Ratti, R. (2014) · Advances in Chemistry · doi:10.1155/2014/729842 · Cited by 286
Chen, S. S., Maneerung, T., Tsang, D. C. W., Ok, Y. S., & Wang, C.-H. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.020 · Cited by 258
Ionic liquids for biofuel production: Opportunities and challenges
Liu, C.-Z., Wang, F., Stiles, A. R., & Guo, C. (2012) · Applied Energy · doi:10.1016/j.apenergy.2011.11.031 · Cited by 236
Yan, J., Zhao, Y., Li, K., Zhang, H., Fan, L., & Lu, Z. (2020) · Chemical Engineering and Processing - Process Intensification · doi:10.1016/j.cep.2020.107870 · Cited by 52
Metadata
- Authors
- Zhang, L., Xian, M., He, Y., Li, L., Yang, J., Yu, S., & Xu, X.
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2009-10
- Volume
- 100
- Issue
- 19
- Pages
- 4368-4373
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W1990982567
- Cited by
- 222
- References
- 1
- FWCI
- 9.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, L., Xian, M., He, Y., Li, L., Yang, J., Yu, S., & Xu, X. (2009). A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols. Bioresource Technology. https://doi.org/10.1016/j.biortech.2009.04.012
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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