Cited by 142Thermochemical Biomass Conversion ProcessesAlgal biology and biofuel productionCoal Properties and Utilization

Study on two-step hydrothermal liquefaction of macroalgae for improving bio-oil

Wang, Shuang, Zhao, Shuang, Cheng, Xiaoxue, Qian, Lili, Barati, Bahram, Gong, Xun, Cao, Bin, Yuan, Chuan·2021·Bioresource Technology

Abstract

In this work, the conversion of Enteromorpha clathrata into bio-oil through hydrothermal liquefaction (HTL) was investigated under different preparation conditions. A two-step reaction method was compared with single-step reaction. At a high temperature, bio-oil produced through the two-step hydrothermal reaction displayed slight changes in yield, but solid residue rate was low. The liquid-to-material ratio of the optimal preparation condition was 40/4 (mL/g). Bio-oil produced in each experiment at this ratio was further analyzed using GC/MS. Furthermore, density functional theory (DFT) quantitative calculation was used in analyzing and proving the possible reaction path of the conversion of furan compounds to aromatic compounds during a direct high-temperature liquefaction process. Results revealed that the two-step method can ensure a high bio-oil yield, while preventing the occurrence of side reactions caused by long-term high-temperature reactions, and improve the bio-oil quality.

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Crossref · 10.1016/j.biortech.2020.124176

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References 50 · Cited by 142

Authors
Wang, S., Zhao, S., Cheng, X., Qian, L., Barati, B., Gong, X., Cao, B., & Yuan, C.
Affiliations
  • Jiangsu University (CN)
  • State Key Laboratory of Coal Combustion (CN)
Corresponding author
Gong, Xun
Venue
Bioresource Technology
Publisher
Elsevier BV
Published
2021-01
Volume
319
Pages
124176
ISSN
0960-8524 (ISSN-L)
OpenAlex
W3089373602
Cited by
142
References
50
Citations by year
2026: 21 · 2025: 10 · 2024: 15 · 2023: 17 · 2022: 56 · 2021: 23
FWCI
7.54
Type
journal article
Language
en
Open access
closed
Locations
  • Bioresource Technology (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • Foundation of State Key Laboratory of Coal Combustion
  • Natural Science Foundation of Jiangsu Province
  • China Postdoctoral Science Foundation
  • Natural Science Research of Jiangsu Higher Education Institutions of China
Topics
  • Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Algal biology and biofuel production
  • Physical Sciences › Engineering › Ocean Engineering › Coal Properties and Utilization
Keywords
hydrothermal liquefaction, seaweed, Enteromorpha clathrata, bio-oil, bio-oil quality, liquid-to-solid ratio, furan derivatives, aromatic compounds, reaction pathways, side reactions, solid residue
MeSH terms
Plant Oils, Seaweed, Temperature, Water, Biomass, Biofuels, Polyphenols

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