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Cited by 27Catalysis for Biomass ConversionCatalysis and Hydrodesulfurization StudiesCatalysts for Methane Reforming

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Selective regulation of products for guaiacol hydrodeoxygenation by adjusting type and acidity of supports

Lin, Min, Jiang, Daxin, Yan, Yuhao, Zhan, Lulu, Song, Xianliang, Li, Rui, Wu, Yulong·2024·Bioresource Technology
DOI 10.1016/j.biortech.2024.131478
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Abstract

Upgrading lignin-oil into advanced fuels or chemicals has been widely studied in recent years. To understand the effect of support type and acidity on the hydrodeoxygenation (HDO) of guaiacol (lignin-oil model compound), Ni-based catalysts were prepared with SiO 2, Al 2 O 3 and ZSM-5 as supports, respectively. The catalysts were characterized by X-ray diffraction (XRD), N 2 adsorption desorption, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and Pyridine adsorption Fourier-transform infrared (Py-IR). The research results indicate that selective regulation of guaiacol hydrogenation products can be achieved by changing the type and acidity of support. Cyclohexanol is the main product over Ni/SiO 2, while cyclohexane is the main product over Ni/ZSM-5 series catalysts. Moreover, as the Si/Al ratio increases, the catalytic activity of Ni/ZSM-5 slightly decreases, and the yield of cyclohexane also decreases. The Brønsted acidity of the support is the key to promoting the conversion of cyclohexanol to cyclohexane. The formation of NiAl 2 O 4 is the main reason for the relatively low activity of Ni/Al 2 O 3. The conversion of guaiacol is as high as 99.2 %, and the yield of cyclohexane is as high as 86.6 % over Ni/ZSM-5(Si/Al = 27). In addition, complete conversion of guaiacol and 92.6 % yield of cyclohexanol were achieved over Ni/SiO 2. More importantly, Ni/SiO 2 and Ni/ZSM-5(27) are suitable for aromatic substrates with different substituents, respectively.

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Metadata

Authors
Lin, M., Jiang, D., Yan, Y., Zhan, L., Song, X., Li, R., & Wu, Y.
Affiliations
  • Beijing Forestry University (CN)
  • Xinjiang University (CN)
Corresponding author
  • Li, Rui
  • Wu, Yulong
ORCID
Venue
Bioresource Technology
Publisher
Elsevier BV
Published
2024-12
Volume
413
Pages
131478
ISSN
0960-8524 (ISSN-L)
DOI
10.1016/j.biortech.2024.131478
OpenAlex
W4402390722
Cited by
27
References
34
Citations by year
2026: 16 · 2025: 11
FWCI
2.95
Type
journal article
Language
en
Open access
closed
Licence
Locations
  • Bioresource Technology (publishedVersion)
  • PubMed (publishedVersion)
Funders
National Natural Science Foundation of China (22378228, 21838006)
Topics
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Hydrodesulfurization Studies
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords
guaiacol, hydrodeoxygenation, Ni-based catalysts, support acidity, Brønsted acidity, ZSM-5, SiO2 support, alumina support, cyclohexanol, cyclohexane, product selectivity, NiAl2O4 formation, Si/Al ratio, aromatic compounds
MeSH terms
Adsorption, Aluminum Oxide, Catalysis, Cyclohexanes, Guaiacol, Hydrogen-Ion Concentration, Hydrogenation, Nickel, Oxygen, Silicon Dioxide, X-Ray Diffraction, Spectroscopy, Fourier Transform Infrared, Photoelectron Spectroscopy

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