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Effect of glycerol on the morphology of nanocomposites made from thermoplastic starch and starch nanocrystals
Open accessAbstract
Abstract Fully bio-based nanocomposites were prepared using starch nanoparticles obtained by acidic hydrolysis of waxy maize starch granules as reinforcement. The same type of starch, which contains 99 wt.% amylopectin, was used to prepare glycerol plasticized and unplasticized matrices. The X-ray diffraction pattern of the plasticized reinforced materials displays both A and B-type peaks, showing that the crystalline structure of the nanocrystals was not affected by processing. The storage modulus of the composite material increases, with respect to the unfilled film, by 470% at 50 °C, while the permeability increases by 70%. This is probably due to a good association of glycerol with the nanoparticles leading to a fibrillar structure, studied by scanning electron microscopy of plasticized and unplasticized composites.
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Cites
Plasticized starch/tunicin whiskers nanocomposites. 1. Structural analysis
Anglès, M. N., & Dufresne, A. (2000) · Macromolecules · doi:10.1021/ma0008701 · Cited by 667
Self-citationImprovement of starch film performances using cellulose microfibrils
Dufresne, A., & Vignon, M. R. (1998) · Macromolecules · doi:10.1021/ma971532b · Cited by 409
Self-citationMorphological investigation of nanocomposites from sorbitol plasticized starch and tunicin whiskers
Mathew, A. P., & Dufresne, A. (2002) · Biomacromolecules · doi:10.1021/bm0101769 · Cited by 384
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Cited by
Preparation, characterization and utilization of starch nanoparticles
Kim, H.-Y., Park, S. S., & Lim, S.-T. (2015) · Colloids and Surfaces B: Biointerfaces · doi:10.1016/j.colsurfb.2014.11.011 · Cited by 419
Preparation and application of starch nanoparticles for nanocomposites: A review
Le Corre, D., & Angellier-Coussy, H. (2014) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2014.09.020 · Cited by 271
Processing of edible films based on nanoreinforced gelatinized starch
Sessini, V., Arrieta, M. P., Kenny, J. M., & Peponi, L. (2016) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2016.02.026 · Cited by 106
Metadata
- Authors
- García, N. L., Ribba, L., Dufresne, A., Aranguren, M., & Goyanes, S.
- Venue
- Carbohydrate Polymers
- Publisher
- Elsevier BV
- Published
- 2011-02
- Volume
- 84
- Issue
- 1
- Pages
- 203-210
- ISSN
- 0144-8617 (ISSN-L)
- OpenAlex
- W2009483787
- Cited by
- 230
- References
- 3
- FWCI
- 2.32
- Type
- journal article
- Language
- en
- Open access
- green
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- García, N. L., Ribba, L., Dufresne, A., Aranguren, M., & Goyanes, S. (2011). Effect of glycerol on the morphology of nanocomposites made from thermoplastic starch and starch nanocrystals. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2010.11.024
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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