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Cited by 87Thermal and Kinetic AnalysisPolysaccharides Composition and ApplicationsThermochemical Biomass Conversion Processes

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Thermal degradation behavior and kinetic analysis of spruce glucomannan and its methylated derivatives

Moriana, Rosana, Zhang, Yujia, Mischnick, Petra, Li, Jiebing, Ek, Monica·2014·Carbohydrate Polymers
DOI 10.1016/j.carbpol.2014.01.086
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Abstract

The thermal degradation behavior and kinetics of spruce glucomannan (SGM) and its methylated derivatives were investigated using thermogravimetric analysis to characterize its temperature-dependent changes for use in specific applications. The results were compared with those obtained for commercial konjac glucomannan (KGM). The SGM and the KGM exhibited two overlapping peaks from 200 to 375°C, which correspond to the intensive devolatilization of more than 59% of the total weight. Differences in the pyrolysis-product distributions and thermal stabilities appeared as a result of the different chemical compositions and molecular weights of the two GMs. The Friedman and Flynn-Wall-Ozawa isoconversional methods and the Coats-Redfern were adopted to determine the kinetic triplet of the intensive devolatilization region. Both GMs can be modeled using a complex mechanism that involves both a Dn-type and an Fn-type reaction. The comparative study of partially methylated GM indicated higher homogeneity and thermal resistance for the material with the higher degree of substitution.

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Metadata

Authors
Moriana, R., Zhang, Y., Mischnick, P., Li, J., & Ek, M.
Affiliations
  • KTH Royal Institute of Technology (SE)
  • Technische Universität Braunschweig (DE)
  • Wallenberg Wood Science Center (SE)
Corresponding author
Ek, Monica
ORCID
Venue
Carbohydrate Polymers
Publisher
Elsevier BV
Published
2014-06
Volume
106
Pages
60-70
ISSN
0144-8617 (ISSN-L)
DOI
10.1016/j.carbpol.2014.01.086
OpenAlex
W1990979295
Cited by
87
References
1
Citations by year
2026: 5 · 2025: 7 · 2024: 11 · 2023: 9 · 2022: 9 · 2021: 4 · 2020: 4 · 2019: 2 · 2018: 9 · 2017: 8 · 2016: 13 · 2015: 5 · 2014: 1
FWCI
4.08
Type
journal article
Language
en
Open access
closed
Licence
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations
  • Carbohydrate Polymers (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
  • Life Sciences › Agricultural and Biological Sciences › Food Science › Polysaccharides Composition and Applications
  • Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
Keywords
konjac glucomannan, thermal degradation, devolatilization, pyrolysis products, thermal stability, degree of substitution, kinetic triplet, model-free kinetics
MeSH terms
Cathartics, Hot Temperature, Kinetics, Mannans, Methylation, Thermogravimetry, Picea

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