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Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid-phase
Open accessAbstract
Abstract Bimetallic PtSn catalysts, containing different amounts of tin, were obtained by means of controlled surface reactions and used in the liquid-phase hydrogenation of furfural. All the studied systems allowed to obtain fufuryl alcohol with high selectivity (96–98%). A minor product was detected when alcoholic solvent were employed, coming from the reaction between furfuryl alcohol and the solvent. Nonalcoholic and non-polar solvents caused a drastic activity decrease. When used in consecutive hydrogenation reactions, the bimetallic catalysts showed a certain deactivation (25% between the first and third cycle), but still they were very selective to furfuryl alcohol. The most efficient system was the catalyst with the lowest tin content (PtSn 0.3 ).
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Cited by
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels
Mariscal, R., Maireles-Torres, P., Ojeda, M., Sádaba, I., & López Granados, M. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02666k · Cited by 1,642
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts
Yu, W., Porosoff, M. D., & Chen, J. G. (2012) · Chemical Reviews · doi:10.1021/cr300096b · Cited by 1,253
Furfural: A Promising Platform Compound for Sustainable Production of C4 and C5 Chemicals
Li, X., Jia, P., & Wang, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01838 · Cited by 834
Nakagawa, Y., Nakazawa, H., Watanabe, H., & Tomishige, K. (2012) · ChemCatChem · doi:10.1002/cctc.201200218 · Cited by 284
Metadata
- Authors
- Merlo, A. B., Vetere, V., Ruggera, J. F., & Casella, M. L.
- Venue
- Catalysis Communications
- Publisher
- Elsevier BV
- Published
- 2009-07
- Volume
- 10
- Issue
- 13
- Pages
- 1665-1669
- ISSN
- 1566-7367 (ISSN-L)
- OpenAlex
- W2020873175
- Cited by
- 254
- References
- 0
- FWCI
- 5.24
- Type
- journal article
- Language
- en
- Open access
- green
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- Merlo, A. B., Vetere, V., Ruggera, J. F., & Casella, M. L. (2009). Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid-phase. Catalysis Communications. https://doi.org/10.1016/j.catcom.2009.05.005
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