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Insights into heterogeneous catalytic activation of peroxymonosulfate by Pd/g-C3N4: The role of superoxide radical and singlet oxygen

Open access
Wang, Yanbin, Cao, Di, Liu, Man, Zhao, Xu·2017·Catalysis Communications

Abstract

Abstract Pd nanoparticles anchored on graphitic nitride carbon (Pd/g-C 3 N 4 ) hybrid catalytic system was prepared by a simple KBH 4 reduction method. Pd/g-C 3 N 4 was very active in the degradation of bisphenol A (BPA) by efficiently activating peroxymonosulfate (PMS). Important influencing factors, such as catalyst dosage, PMS concentration, pH and reaction temperature for the BPA removal were investigated. Pd/g-C 3 N 4 -PMS demonstrated a wide effective pH range, namely 3.0–9.0. Radical quenching tests and electron spin response (ESR) analyses revealed that superoxide radical (O 2 − ) and singlet oxygen ( 1 O 2 ) instead of sulfate radical (SO 4 − ) and hydroxyl radicals ( OH) were the major oxidized species for the degradation of BPA.

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Metadata

Authors
Wang, Y., Cao, D., Liu, M., & Zhao, X.
Venue
Catalysis Communications
Publisher
Elsevier BV
Published
2017-12
Volume
102
Pages
85-88
ISSN
1566-7367 (ISSN-L)
OpenAlex
W2742845556
Cited by
173
References
4
FWCI
9.23
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Insights into heterogeneous catalytic activation of peroxymonosulfate by Pd/g-C3N4: The role of superoxide radical and singlet oxygen. https://app.cochat.ai/papers/10.1016/j.catcom.2017.08.016
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Wang, Y., Cao, D., Liu, M., & Zhao, X. (2017). Insights into heterogeneous catalytic activation of peroxymonosulfate by Pd/g-C3N4: The role of superoxide radical and singlet oxygen. Catalysis Communications. https://doi.org/10.1016/j.catcom.2017.08.016

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