The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
POP-type ligands: Variable coordination and hemilabile behaviour
Open accessAbstract
Hemilabile ligands – ligands containing two or more potential donors to a metal centre, of which one or more can dissociate – have the ability to provide a transition metal complex with open coordination sites at which reactivity can occur, or stabilise low coordinate intermediates along reaction pathways. POP-type ligands and in particular POP, Xantphos, DBFphos and DPEphos-based ligands contain three possible binding sites: two phosphines and an ether linker, thus have the potential to show κ1-, κ2- or κ3-binding modes. This review summarises the examples where POP-type ligands display hemilabile, or closely related variable coordination, characteristics in either synthesis or catalysis.
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The Cambridge Structural Database
Groom, C. R., Bruno, I. J., Lightfoot, M. P., & Ward, S. C. (2016) · Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials · doi:10.1107/s2052520616003954 · Cited by 10,297
Cited by
Iodine capture in porous organic polymers and metal–organic frameworks materials
Xie, W., Cui, D., Zhang, S.-R., Xu, Y.-H., & Jiang, D.-L. (2019) · Materials Horizons · doi:10.1039/c8mh01656a · Cited by 622
Metadata
- Authors
- Adams, G. M., & Weller, A. S.
- Venue
- Coordination Chemistry Reviews
- Publisher
- Elsevier BV
- Published
- 2018-01
- Volume
- 355
- Pages
- 150-172
- ISSN
- 0010-8545 (ISSN-L)
- OpenAlex
- W2753905986
- Cited by
- 166
- References
- 1
- FWCI
- 6.19
- Type
- journal article
- Language
- en
- Open access
- hybrid
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