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Cited by 325

The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.

Effect of initial pH on the tetracycline (TC) removal by zero-valent iron: Adsorption, oxidation and reduction

Cao, Jinyan, Xiong, Zhaokun, Lai, Bo·2018·Chemical Engineering Journal

Abstract

Abstract In this study, the effect of initial pH on tetracycline (TC) removal by zero-valent iron (ZVI) has been investigated thoroughly. The experimental results show that TC degradation efficiency performed effectively across the initial pH range 2.5–6.5, almost all removal efficiencies in this range reached 90% after 30 min treatment. As pH increasing to alkaline, removal efficiencies gradually decreased. Experimental results indicate that removal of TC by Fe0/air process is mainly attributed to adsorption (by Fe0 and its corrosion products), oxidation and reduction. pH significantly affected the formation of iron corrosion products, the production of hydroxyl radicals (HO ) and the variation of TC species. Adsorption is the main removal path under neutral conditions while oxidation is the prime removal way under acidic conditions. Finally, the intermediates and toxicity analysis indicates that less toxicity products generated through ring-opening reactions. The study provides new insight into the removal of TC by ZVI and support a theoretical foundation for further research.

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Metadata

Authors
Cao, J., Xiong, Z., & Lai, B.
Venue
Chemical Engineering Journal
Publisher
Elsevier BV
Published
2018-07
Volume
343
Pages
492-499
ISSN
1385-8947 (ISSN-L)
OpenAlex
W2790228449
Cited by
325
References
47
FWCI
10.38
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Effect of initial pH on the tetracycline (TC) removal by zero-valent iron: Adsorption, oxidation and reduction. https://app.cochat.ai/papers/10.1016/j.cej.2018.03.036
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Cao, J., Xiong, Z., & Lai, B. (2018). Effect of initial pH on the tetracycline (TC) removal by zero-valent iron: Adsorption, oxidation and reduction. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2018.03.036

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