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Three dimensional reduced graphene oxide/ZIF-67 aerogel: Effective removal cationic and anionic dyes from water

Yang, Qingxiang, Lu, Ran, Ren, ShuangShuang, Chen, Congtao, Chen, Zhijun, Yang, Xiaoyan·2018·Chemical Engineering Journal

Abstract

Abstract A three dimensional (3D) reduced graphene oxide (rGO)/zeolitic imidazolate framework-67(ZIF-67) aerogel (3D rGO/ZIF-67 aerogel) was prepared via in situ assembly of ZIF-67 polyhedrons on a 3D rGO networks, not only providing multifarious affinity interactions for synergistic promoting the adsorption behavior of organic dyes, but also constructing a holder for ZIF-67 polyhedrons to convenient separation. This porous aerogel displays excellent absorption ability for cationic dyes (crystal violet, CV) and anionic dyes (methyl orange, MO). The maximum adsorption capacities are up to 1714.2 mg·g−1 and 426.3 mg·g−1 for CV and MO, respectively. 3D rGO/ZIF-67 aerogel shows a remarkable promoting of CV adsorption capacity than pure 3D rGO and ZIF-67. The ultrahigh adsorption capability towards cationic CV dyes is mainly driven by π-π interactions and electrostatic interactions between 3D rGO/ZIF-67 aerogel and dye molecules, and synergistic interactions at the interface of 3D rGO and ZIF-67 polyhedrons. The high adsorption capability towards anionic MO dyes is mainly due to the porosity of ZIF-67 polyhedrons and electrostatic attraction between MO and ZIF-67. The multi-component property of 3D rGO/ZIF-67 aerogel shows a great potential application in dye-bearing wastewater treatment.

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Metadata

Authors
Yang, Q., Lu, R., Ren, S., Chen, C., Chen, Z., & Yang, X.
Venue
Chemical Engineering Journal
Publisher
Elsevier BV
Published
2018-09
Volume
348
Pages
202-211
ISSN
1385-8947 (ISSN-L)
OpenAlex
W2800015758
Cited by
326
References
1
FWCI
14.11
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Three dimensional reduced graphene oxide/ZIF-67 aerogel: Effective removal cationic and anionic dyes from water. https://app.cochat.ai/papers/10.1016/j.cej.2018.04.176
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Yang, Q., Lu, R., Ren, S., Chen, C., Chen, Z., & Yang, X. (2018). Three dimensional reduced graphene oxide/ZIF-67 aerogel: Effective removal cationic and anionic dyes from water. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2018.04.176

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