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Efficient degradation of nitrobenzene by Cu-Co-Fe-LDH catalyzed peroxymonosulfate to produce hydroxyl radicals

Lu, Hongtao, Sui, Minghao, Yuan, Bojie, Wang, Jingyu, Lv, Yanning·2019·Chemical Engineering Journal

Abstract

Abstract Advanced oxidation processes (AOPs) are effective means of treating organic contamination in water. There are many applications for AOPs based on peroxymonosulfate (PMS). In this work, a novel layered double hydroxide (Cu-Co-Fe-LDH) was synthesized to activate PMS for nitrobenzene (NB) degradation. Cu-Co-Fe-LDH exhibited a notably catalytic activity on PMS for NB degradation. Cu-Co-Fe-LDH/PMS could degrade NB efficiently and rapidly under a wide pH condition. When PMS dosage was 0.5 mM and Cu-Co-Fe-LDH dosage was 0.1 g·L−1, it took 6 min to completely degrade 2 mg·L−1 NB (about 16 μM). The hydroxyl radicals played the dominant role in the degradation of NB. A large number of hydroxyl radicals were generated in the process even under acidic or neutral conditions. The work here further expanded the scope of application of PMS activation systems. The prominent catalytic activity and notable stability made Cu-Co-Fe-LDH a potential catalyst for practical use.

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Metadata

Authors
Lu, H., Sui, M., Yuan, B., Wang, J., & Lv, Y.
Venue
Chemical Engineering Journal
Publisher
Elsevier BV
Published
2019-02
Volume
357
Pages
140-149
ISSN
1385-8947 (ISSN-L)
OpenAlex
W2892206169
Cited by
275
References
2
FWCI
9.34
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Efficient degradation of nitrobenzene by Cu-Co-Fe-LDH catalyzed peroxymonosulfate to produce hydroxyl radicals. https://app.cochat.ai/papers/10.1016/j.cej.2018.09.111
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Lu, H., Sui, M., Yuan, B., Wang, J., & Lv, Y. (2019). Efficient degradation of nitrobenzene by Cu-Co-Fe-LDH catalyzed peroxymonosulfate to produce hydroxyl radicals. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2018.09.111

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