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Heterogeneous activation of peroxymonosulfate by CoMgFe-LDO for degradation of carbamazepine: Efficiency, mechanism and degradation pathways
Abstract
Abstract In this study, composite CoMgFe-LDO catalyst was synthesized from layered double hydroxides precursor and tested as a heterogeneous catalyst to activate peroxymonosulfate (PMS) for carbamazepine (CBZ) degradation. X-ray powder diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS) were used to characterize CoMgFe-LDO. CoMgFe-LDO exhibited much better catalytic performance than the control catalysts. Operational parameters of CoMgFe-LDO dosage, PMS dosage, initial solution pH and initial CBZ concentration on the degradation efficiency were investigated. Complete removal of 5 mg/L CBZ was achieved with 20 mg/L CoMgFe-LDO and 0.2 mM PMS at pH 5.8 in 20 min reaction time. Meanwhile, the inorganic anions effects in the CoMgFe-LDO/PMS system for CBZ removal and the catalytic stability were also studied. The radical scavenging experiments confirmed that both SO4 − and HO were involved and SO4 − played a dominant role on the CBZ degradation. In addition, the possible reaction mechanism of CoMgFe-LDO/PMS system for CBZ removal was proposed. Finally, the degradation pathways of CBZ were proposed by the CBZ degradation intermediates identified by Ultra Performance liquid chromatography coupled with quadrupole time-of-flight mass spectrometry technologies (UPLC-QTOF-MS/MS).
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Wang, J., & Wang, S. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.11.059 · Cited by 4,087
Heberer, T. (2002) · Toxicology Letters · doi:10.1016/s0378-4274(02)00041-3 · Cited by 2,995
Cited by
Huang, B., Wu, Z., Wang, X., Song, X., Zhou, H., Zhang, H., Zhou, P., Liu, W., Xiong, Z., & Lai, B. (2023) · Environmental Science & Technology · doi:10.1021/acs.est.3c05509 · Cited by 281
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Metadata
- Authors
- Hong, Y., Zhou, H., Xiong, Z., Liu, Y., Yao, G., & Lai, B.
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2020-07
- Volume
- 391
- Pages
- 123604
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W2990523742
- Cited by
- 224
- References
- 2
- FWCI
- 7.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hong, Y., Zhou, H., Xiong, Z., Liu, Y., Yao, G., & Lai, B. (2020). Heterogeneous activation of peroxymonosulfate by CoMgFe-LDO for degradation of carbamazepine: Efficiency, mechanism and degradation pathways. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2019.123604
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