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Foam-to-adhesive recycling of self-blown non-isocyanate polyurethane foams facilitated by integration of disulfide exchangeable bonds and moisture
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References 83 · Cited by 24
Research works printed but not linked: 81
- Delavarde, 2024, Sustainable polyurethanes: toward new cutting-edge opportunities, Prog. Polym. Sci., 151, 10.1016/j.progpolymsci.2024.101805 · DOI
- Liang, 2021, Material flows of polyurethane in the United States, Environ. Sci. Technol., 55, 14215, 10.1021/acs.est.1c03654 · DOI
- Niesiobędzka, 2023, Challenges and recent advances in bio-based isocyanate production, Green Chem., 25, 2482, 10.1039/D2GC04644J · DOI
- Peyrton, 2021, Structure-properties relationships of cellular materials from biobased polyurethane foams, Mater. Sci. Eng. R. Rep., 145, 10.1016/j.mser.2021.100608 · DOI
- Ates, 2022, Polyurethane foam materials and their industrial applications, Polym. Int., 71, 1157, 10.1002/pi.6441 · DOI
- Monie, 2021, Self-foaming polymers: Opportunities for the next generation of personal protective equipment, Mater. Sci. Eng. R. Rep., 145, 10.1016/j.mser.2021.100628 · DOI
- Liu, 2023, Opportunities in closed-loop molecular recycling of end-of-life polyurethane, ACS Sustain. Chem. Eng., 11, 6114, 10.1021/acssuschemeng.2c07422 · DOI
- Akindoyo, 2016, Polyurethane types, synthesis and applications – a review, RSC Adv., 6, 114453, 10.1039/C6RA14525F · DOI
- Sheppard, 2020, Reprocessing postconsumer polyurethane foam using carbamate exchange catalysis and twin-screw extrusion, ACS Cent. Sci., 6, 921, 10.1021/acscentsci.0c00083 · DOI
- Sun, 2023, Green catalysts for reprocessing thermoset polyurethanes, Macromolecules, 56, 6978, 10.1021/acs.macromol.3c01116 · DOI
- Quienne, 2022, Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop, ACS Sustain. Chem. Eng., 10, 7041, 10.1021/acssuschemeng.2c00950 · DOI
- Kim, 2024, Thermal activation of Zirconium(IV) acetylacetonate catalysts to enhance polyurethane synthesis and reprocessing, Macromolecules, 57, 6759, 10.1021/acs.macromol.4c00625 · DOI
- Bakkali-Hassani, 2022, Transcarbamoylation in polyurethanes: underestimated exchange reactions?, Macromolecules, 55, 7974, 10.1021/acs.macromol.2c01184 · DOI
- Bandegi, 2022, Vitrimerization of rigid thermoset polyurethane foams: A mechanochemical method to recycle and reprocess thermosets, Polym. Adv. Technol., 33, 3750, 10.1002/pat.5827 · DOI · Paper page
- Kim, 2023, Circular Reprocessing of thermoset polyurethane foams, Adv. Mater., 35, 10.1002/adma.202305387 · DOI
- Zhong, 2021, Hot-melt adhesive based on dynamic oxime-carbamate bonds, Ind. Eng. Chem. Res., 60, 6925, 10.1021/acs.iecr.1c00768 · DOI
- Wang, 2019, Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive, Mater. Chem. Front., 3, 1833, 10.1039/C9QM00233B · DOI
- Kassem, 2024, Foam‐to‐foam recycling potential of PU‐foams by integration of amino esters, Adv. Funct. Mater., 34, 10.1002/adfm.202409263 · DOI · Paper page
- Unal, 2024, Foam-to-elastomer recycling of polyurethane materials through incorporation of dynamic covalent TAD-indole linkages, ACS Appl. Polym. Mater., 6, 2604, 10.1021/acsapm.3c02791 · DOI
- Wang, 2021, Malleable and thermally recyclable polyurethane foam, Green Chem., 23, 307, 10.1039/D0GC03471A · DOI
- Liu, 2022, Improving thermal reprocessability of commercial flexible polyurethane foam by vitrimer modification of the hard segments, ACS Appl. Polym. Mater., 4, 5056, 10.1021/acsapm.2c00595 · DOI
- Zhang, 2021, Renewable castor-oil-based waterborne polyurethane networks: simultaneously showing high strength, self-healing, processability and tunable multishape memory, Angew. Chem. Int. Ed., 60, 4289, 10.1002/anie.202014299 · DOI
- Zhou, 2025, High-performance, high biobased content, self-repairable, and recyclable biobased photopolymers for UV-curing 3D printing, Ind. Crop. Prod., 224, 10.1016/j.indcrop.2024.120299 · DOI
- Zeng, 2023, Sustainable polyurethane networks with high self-healing and mechanical properties based on dual dynamic covalent bonds, Macromol. Chem. Phys., 224, 10.1002/macp.202200322 · DOI
- Blattmann, 2016, Flexible and bio‐based nonisocyanate polyurethane (NIPU) foams, Macromol. Mater. Eng., 301, 944, 10.1002/mame.201600141 · DOI
- Grignard, 2016, CO 2 -blown microcellular non-isocyanate polyurethane (NIPU) foams: from bio- and CO 2 -sourced monomers to potentially thermal insulating materials, Green Chem., 18, 2206, 10.1039/C5GC02723C · DOI
- Dong, 2021, Assessment of plant and microalgal oil-derived nonisocyanate polyurethane products for potential commercialization, ACS Sustain. Chem. Eng., 9, 12858, 10.1021/acssuschemeng.1c03653 · DOI
- Cornille, 2015, A new way of creating cellular polyurethane materials: NIPU foams, Eur. Polym. J., 66, 129, 10.1016/j.eurpolymj.2015.01.034 · DOI
- Cornille, 2016, Room temperature flexible isocyanate-free polyurethane foams, Eur. Polym. J., 84, 873, 10.1016/j.eurpolymj.2016.05.032 · DOI
- Coste, 2022, Non-isocyanate polyurethane foams based on six-membered cyclic carbonates, Eur. Polym. J., 176, 10.1016/j.eurpolymj.2022.111392 · DOI
- Purwanto, 2023, Rapidly synthesized, self-blowing, non-isocyanate polyurethane network foams with reprocessing to bulk networks via hydroxyurethane dynamic chemistry, Polymer (Guildf), 272, 10.1016/j.polymer.2023.125858 · DOI
- Purwanto, 2023, Reprocessable, bio-based, self-blowing non-isocyanate polyurethane network foams from cashew nutshell liquid, ACS Appl. Polym. Mater., 5, 6651, 10.1021/acsapm.3c01196 · DOI
- Monie, 2020, Chemo‐ and regioselective additions of nucleophiles to cyclic carbonates for the preparation of self‐blowing non‐isocyanate polyurethane foams, Angew. Chem. Int. Ed., 59, 17033, 10.1002/anie.202006267 · DOI
- Bourguignon, 2022, Water‐induced self‐blown non‐isocyanate polyurethane foams, Angew. Chem. Int. Ed., 61, 10.1002/anie.202213422 · DOI
- Bourguignon, 2024, Cascade exotherms for rapidly producing hybrid nonisocyanate polyurethane foams from room temperature formulations, J. Am. Chem. Soc., 146, 988, 10.1021/jacs.3c11637 · DOI
- Monie, 2022, Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams, ACS Macro Lett., 11, 236, 10.1021/acsmacrolett.1c00793 · DOI · Paper page
- Makarov, 2025, Advancing non-isocyanate polyurethane foams: exo -vinylene cyclic carbonate–amine chemistry enabling room-temperature reactivity and fast self-blowing, Macromolecules, 58, 1673, 10.1021/acs.macromol.4c02894 · DOI
- Bourguignon, 2025, Fast, catalyst-free room temperature production of isocyanate-free polyurethane foams using aromatic thiols, Polym. Chem., 16, 192, 10.1039/D4PY00971A · DOI
- Chen, 2024, Biobased, catalyst-free non-isocyanate polythiourethane foams: Highly dynamic nature affords fast reprocessability, extrudability and refoamability, Chem. Eng. J., 496, 10.1016/j.cej.2024.154035 · DOI
- Purwanto, 2024, Biobased, reprocessable, self-blown non-isocyanate polyurethane foams: Influence of blowing agent structure and functionality, Eur. Polym. J., 206, 10.1016/j.eurpolymj.2024.112775 · DOI
- Wang, 2024, Self-blowing non-isocyanate polyurethane foams from cyclic carbonate linseed oil, ACS Sustainable Resour Manage, 1, 462, 10.1021/acssusresmgt.3c00103 · DOI
- Sternberg, 2020, Materials for the biorefinery: high bio-content, shape memory Kraft lignin-derived non-isocyanate polyurethane foams using a non-toxic protocol, Green Chem., 22, 6922, 10.1039/D0GC01659D · DOI
- Ghasemlou, 2019, Bio-based routes to synthesize cyclic carbonates and polyamines precursors of non-isocyanate polyurethanes: A review, Eur. Polym. J., 118, 668, 10.1016/j.eurpolymj.2019.06.032 · DOI
- Trojanowska, 2024, Valorization of waste biomass for the fabrication of isocyanate-free polyurethane foams, Green Chem., 26, 8383, 10.1039/D4GC01547A · DOI
- Bakkali-Hassani, 2023, Polyhydroxyurethane covalent adaptable networks: looking for suitable catalysts, Polym. Chem., 14, 3610, 10.1039/D3PY00579H · DOI
- Chen, 2017, Reprocessable polyhydroxyurethane networks exhibiting full property recovery and concurrent associative and dissociative dynamic chemistry: Via transcarbamoylation and reversible cyclic carbonate aminolysis, Polym. Chem., 8, 6349, 10.1039/C7PY01160A · DOI
- Wang, 2024, Reprocessable, self-healing, and creep-resistant covalent adaptable network made from chain-growth monomers with dynamic covalent thionourethane and disulfide cross-links, ACS Macro. Lett., 13, 1147, 10.1021/acsmacrolett.4c00391 · DOI
- Chen, 2024, Non-isocyanate polythiourethane network from biowaste: achieving circularity via multidimensional chemical recycling with valuable small-molecule recovery and reprocessability by understanding the dynamic chemistry, Macromolecules, 57, 490, 10.1021/acs.macromol.3c01941 · DOI
- Pronoitis, 2022, Structurally diverse and recyclable isocyanate-free polyurethane networks from CO2-derived cyclic carbonates, ACS Sustain Chem Eng, 10, 2522, 10.1021/acssuschemeng.1c08530 · DOI
- Fortman, 2018, Rapidly reprocessable cross-linked polyhydroxyurethanes based on disulfide exchange, ACS Macro Lett., 7, 1226, 10.1021/acsmacrolett.8b00667 · DOI
- Li, 2020, Covalent adaptive networks for enhanced adhesion: exploiting disulfide dynamic chemistry and annealing during application, ACS Appl. Polym. Mater., 2, 4658, 10.1021/acsapm.0c00720 · DOI
- Chen, 2023, Biobased, reprocessable non-isocyanate polythiourethane networks with thionourethane and disulfide cross-links: comparison with polyhydroxyurethane network analogues, Macromolecules, 56, 3687, 10.1021/acs.macromol.3c00220 · DOI
- Panchireddy, 2017, Reinforced poly(hydroxyurethane) thermosets as high performance adhesives for aluminum substrates, Polym. Chem., 8, 5897, 10.1039/C7PY01209H · DOI
- Alferiev, 2005, A novel mercapto-bisphosphonate as an efficient anticalcification agent for bioprosthetic tissues, J. Organomet. Chem., 690, 2543, 10.1016/j.jorganchem.2004.10.011 · DOI
- Jayson, 1967, The radiation chemistry of cystamine sulphate, J. Chem. Soc. B, 944, 10.1039/j29670000944 · DOI
- Fortman, 2017, Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes, J. Appl. Polym. Sci., 134, 44984, 10.1002/app.44984 · DOI
- Monie, 2024, The Multifaceted role of water as an accelerator for the preparation of isocyanate-free polyurethane thermosets, Macromolecules, 57, 8877
- Van Lijsebetten, 2022, Characterising different molecular landscapes in dynamic covalent networks, Chem. Sci., 13, 12865, 10.1039/D2SC05528G · DOI
- Deng, 2012, Dynamic hydrogels with an environmental adaptive self-healing ability and dual responsive Sol-Gel transitions, ACS Macro Lett., 1, 275, 10.1021/mz200195n · DOI
- Luo, 2018, Chemomechanics in the moisture-induced malleability of polyimine-based covalent adaptable networks, Macromolecules, 51, 9825, 10.1021/acs.macromol.8b02046 · DOI
- Taynton, 2014, Heat- or water-driven malleability in a highly recyclable covalent network polymer, Adv. Mater., 26, 3938, 10.1002/adma.201400317 · DOI · Paper page
- Sen Choong, 2021, Biobased nonisocyanate polyurethanes as recyclable and intrinsic self-healing coating with triple healing sites, ACS Macro Lett., 10, 635, 10.1021/acsmacrolett.1c00163 · DOI
- Panchireddy, 2018, Bio-based poly(hydroxyurethane) glues for metal substrates, Polym. Chem., 9, 2650, 10.1039/C8PY00281A · DOI
- Panchireddy, 2018, Catechol containing polyhydroxyurethanes as high-performance coatings and adhesives, ACS Sustain. Chem. Eng., 6, 14936, 10.1021/acssuschemeng.8b03429 · DOI
- Gomez-Lopez, 2021, Poly(hydroxyurethane) adhesives and coatings: state-of-the-art and future directions, ACS Sustain. Chem. Eng., 9, 9541, 10.1021/acssuschemeng.1c02558 · DOI
- Matos-Pérez, 2012, Polymer composition and substrate influences on the adhesive bonding of a biomimetic, cross-linking polymer, J. Am. Chem. Soc., 134, 9498, 10.1021/ja303369p · DOI
- Michal, 2016, Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer, ACS Appl. Mater. Interfaces, 8, 11041, 10.1021/acsami.6b01251 · DOI
- Canadell, 2011, Self-healing materials based on disulfide links, Macromolecules, 44, 2536, 10.1021/ma2001492 · DOI
- Imbernon, 2015, Chemically crosslinked yet reprocessable epoxidized natural rubber via thermo-activated disulfide rearrangements, Polym. Chem., 6, 4271, 10.1039/C5PY00459D · DOI
- Azcune, 2016, Aromatic disulfide crosslinks in polymer systems: Self-healing, reprocessability, recyclability and more, Eur. Polym. J., 84, 147, 10.1016/j.eurpolymj.2016.09.023 · DOI
- Verdugo, 2024, A biobased epoxy vitrimer with dual relaxation mechanism: A promising material for renewable, reusable, and recyclable adhesives and composites, ACS Sustain. Chem. Eng., 12, 5965, 10.1021/acssuschemeng.4c00205 · DOI
- S. Ebnesajjad, A.H. Landrock, Characteristics of Adhesive Materials, in: S. Ebnesajjad, A. H. Landrock (Eds.), Adhesives Technology Handbook, Elsevier, Amsterdam, 2015: pp. 84–159. https://doi.org/10.1016/B978-0-323-35595-7.00005-X. · DOI
- Van Lijsebetten, 2022, A highly dynamic covalent polymer network without creep: mission impossible?, Angew. Chem. Int. Ed., 61, 10.1002/anie.202210405 · DOI
- Bin Rusayyis, 2021, Reprocessable covalent adaptable networks with excellent elevated-temperature creep resistance: facilitation by dynamic, dissociative bis(hindered amino) disulfide bonds, Polym. Chem., 12, 2760, 10.1039/D1PY00187F · DOI
- Yi, 2020, The bonding between glass and metal, Int. J. Adv. Manuf. Technol., 111, 963, 10.1007/s00170-020-06018-x · DOI
- Overend, 2011, The selection and performance of adhesives for a steel–glass connection, Int. J. Adhes Adhes, 31, 587, 10.1016/j.ijadhadh.2011.06.001 · DOI
- Pereira, 2010, Analysis of manufacturing parameters on the shear strength of aluminium adhesive single-lap joints, J Mater Process Technol, 210, 610, 10.1016/j.jmatprotec.2009.11.006 · DOI
- G. Critchlow, Surface Treatments, in: L.F.M. da Silva, A. Öchsner, R.D. Adams (Eds)., Handbook of Adhesion Technology, in Springer Berlin Heidelberg, Berlin, Heidelberg, 2011: pp. 119-146. https://doi.org/10.1007/978-3-642-01169-6. · DOI
- Bao, 2023, Chemically recyclable supramolecular thermosets toward strong and reusable hot-melt adhesives, Macromolecules, 56, 6633, 10.1021/acs.macromol.3c01063 · DOI
- Tian, 2022, Applications of adhesives in textiles: A review, Eur. Polym. J., 167, 10.1016/j.eurpolymj.2022.111089 · DOI
- Rahman, 2021, Design of tough adhesive from commodity thermoplastics through dynamic crosslinking, Sci. Adv., 7, 10.1126/sciadv.abk2451 · DOI
Metadata
- Authors
- Lechuga-Islas, V. D., Gillissen, E., Bourguignon, M., Grignard, B., & Detrembleur, C.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Grignard, Bruno
- Detrembleur, Christophe
- ORCID
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2025-07
- Volume
- 516
- Pages
- 163998
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W4410529874
- Cited by
- 24
- References
- 83
- Citations by year
- 2026: 18 · 2025: 6
- FWCI
- 5.57
- Type
- journal article
- Language
- en
- Open access
- green
- doi.org
- Licence
- Locations
- Chemical Engineering Journal (publishedVersion)
- ChemRxiv (acceptedVersion, cc-by-nc-nd)
- ORBi (University of Liège) (submittedVersion, other-oa)
- Funders
- Fund for Scientific Research
- Région wallonne
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Foaming and Composites
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- foam recycling, dynamic disulfide bonds, cystamine, adhesive recycling, lap shear strength, polyhydroxyurethanes
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