Cited by 24Polymer composites and self-healingPolymer Foaming and CompositesPolymer crystallization and properties

The DOI matches its Crossref record; the references it cites are not checked yet.

Foam-to-adhesive recycling of self-blown non-isocyanate polyurethane foams facilitated by integration of disulfide exchangeable bonds and moisture

Open access
Lechuga-Islas, Víctor D., Gillissen, Emeline, Bourguignon, Maxime, Grignard, Bruno, Detrembleur, Christophe·2025·Chemical Engineering Journal

Published version of a preprint

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1016/j.cej.2025.163998

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

The citation lists haven’t been fetched yet

References 83 · Cited by 24

Research works printed but not linked: 81

  1. Delavarde, 2024, Sustainable polyurethanes: toward new cutting-edge opportunities, Prog. Polym. Sci., 151, 10.1016/j.progpolymsci.2024.101805 · DOI
  2. Liang, 2021, Material flows of polyurethane in the United States, Environ. Sci. Technol., 55, 14215, 10.1021/acs.est.1c03654 · DOI
  3. Niesiobędzka, 2023, Challenges and recent advances in bio-based isocyanate production, Green Chem., 25, 2482, 10.1039/D2GC04644J · DOI
  4. Peyrton, 2021, Structure-properties relationships of cellular materials from biobased polyurethane foams, Mater. Sci. Eng. R. Rep., 145, 10.1016/j.mser.2021.100608 · DOI
  5. Ates, 2022, Polyurethane foam materials and their industrial applications, Polym. Int., 71, 1157, 10.1002/pi.6441 · DOI
  6. Monie, 2021, Self-foaming polymers: Opportunities for the next generation of personal protective equipment, Mater. Sci. Eng. R. Rep., 145, 10.1016/j.mser.2021.100628 · DOI
  7. Liu, 2023, Opportunities in closed-loop molecular recycling of end-of-life polyurethane, ACS Sustain. Chem. Eng., 11, 6114, 10.1021/acssuschemeng.2c07422 · DOI
  8. Akindoyo, 2016, Polyurethane types, synthesis and applications – a review, RSC Adv., 6, 114453, 10.1039/C6RA14525F · DOI
  9. Sheppard, 2020, Reprocessing postconsumer polyurethane foam using carbamate exchange catalysis and twin-screw extrusion, ACS Cent. Sci., 6, 921, 10.1021/acscentsci.0c00083 · DOI
  10. Sun, 2023, Green catalysts for reprocessing thermoset polyurethanes, Macromolecules, 56, 6978, 10.1021/acs.macromol.3c01116 · DOI
  11. Quienne, 2022, Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop, ACS Sustain. Chem. Eng., 10, 7041, 10.1021/acssuschemeng.2c00950 · DOI
  12. Kim, 2024, Thermal activation of Zirconium(IV) acetylacetonate catalysts to enhance polyurethane synthesis and reprocessing, Macromolecules, 57, 6759, 10.1021/acs.macromol.4c00625 · DOI
  13. Bakkali-Hassani, 2022, Transcarbamoylation in polyurethanes: underestimated exchange reactions?, Macromolecules, 55, 7974, 10.1021/acs.macromol.2c01184 · DOI
  14. Bandegi, 2022, Vitrimerization of rigid thermoset polyurethane foams: A mechanochemical method to recycle and reprocess thermosets, Polym. Adv. Technol., 33, 3750, 10.1002/pat.5827 · DOI · Paper page
  15. Kim, 2023, Circular Reprocessing of thermoset polyurethane foams, Adv. Mater., 35, 10.1002/adma.202305387 · DOI
  16. Zhong, 2021, Hot-melt adhesive based on dynamic oxime-carbamate bonds, Ind. Eng. Chem. Res., 60, 6925, 10.1021/acs.iecr.1c00768 · DOI
  17. Wang, 2019, Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive, Mater. Chem. Front., 3, 1833, 10.1039/C9QM00233B · DOI
  18. Kassem, 2024, Foam‐to‐foam recycling potential of PU‐foams by integration of amino esters, Adv. Funct. Mater., 34, 10.1002/adfm.202409263 · DOI · Paper page
  19. Unal, 2024, Foam-to-elastomer recycling of polyurethane materials through incorporation of dynamic covalent TAD-indole linkages, ACS Appl. Polym. Mater., 6, 2604, 10.1021/acsapm.3c02791 · DOI
  20. Wang, 2021, Malleable and thermally recyclable polyurethane foam, Green Chem., 23, 307, 10.1039/D0GC03471A · DOI
  21. Liu, 2022, Improving thermal reprocessability of commercial flexible polyurethane foam by vitrimer modification of the hard segments, ACS Appl. Polym. Mater., 4, 5056, 10.1021/acsapm.2c00595 · DOI
  22. Zhang, 2021, Renewable castor-oil-based waterborne polyurethane networks: simultaneously showing high strength, self-healing, processability and tunable multishape memory, Angew. Chem. Int. Ed., 60, 4289, 10.1002/anie.202014299 · DOI
  23. Zhou, 2025, High-performance, high biobased content, self-repairable, and recyclable biobased photopolymers for UV-curing 3D printing, Ind. Crop. Prod., 224, 10.1016/j.indcrop.2024.120299 · DOI
  24. Zeng, 2023, Sustainable polyurethane networks with high self-healing and mechanical properties based on dual dynamic covalent bonds, Macromol. Chem. Phys., 224, 10.1002/macp.202200322 · DOI
  25. Blattmann, 2016, Flexible and bio‐based nonisocyanate polyurethane (NIPU) foams, Macromol. Mater. Eng., 301, 944, 10.1002/mame.201600141 · DOI
  26. Grignard, 2016, CO 2 -blown microcellular non-isocyanate polyurethane (NIPU) foams: from bio- and CO 2 -sourced monomers to potentially thermal insulating materials, Green Chem., 18, 2206, 10.1039/C5GC02723C · DOI
  27. Dong, 2021, Assessment of plant and microalgal oil-derived nonisocyanate polyurethane products for potential commercialization, ACS Sustain. Chem. Eng., 9, 12858, 10.1021/acssuschemeng.1c03653 · DOI
  28. Cornille, 2015, A new way of creating cellular polyurethane materials: NIPU foams, Eur. Polym. J., 66, 129, 10.1016/j.eurpolymj.2015.01.034 · DOI
  29. Cornille, 2016, Room temperature flexible isocyanate-free polyurethane foams, Eur. Polym. J., 84, 873, 10.1016/j.eurpolymj.2016.05.032 · DOI
  30. Coste, 2022, Non-isocyanate polyurethane foams based on six-membered cyclic carbonates, Eur. Polym. J., 176, 10.1016/j.eurpolymj.2022.111392 · DOI
  31. Purwanto, 2023, Rapidly synthesized, self-blowing, non-isocyanate polyurethane network foams with reprocessing to bulk networks via hydroxyurethane dynamic chemistry, Polymer (Guildf), 272, 10.1016/j.polymer.2023.125858 · DOI
  32. Purwanto, 2023, Reprocessable, bio-based, self-blowing non-isocyanate polyurethane network foams from cashew nutshell liquid, ACS Appl. Polym. Mater., 5, 6651, 10.1021/acsapm.3c01196 · DOI
  33. Monie, 2020, Chemo‐ and regioselective additions of nucleophiles to cyclic carbonates for the preparation of self‐blowing non‐isocyanate polyurethane foams, Angew. Chem. Int. Ed., 59, 17033, 10.1002/anie.202006267 · DOI
  34. Bourguignon, 2022, Water‐induced self‐blown non‐isocyanate polyurethane foams, Angew. Chem. Int. Ed., 61, 10.1002/anie.202213422 · DOI
  35. Bourguignon, 2024, Cascade exotherms for rapidly producing hybrid nonisocyanate polyurethane foams from room temperature formulations, J. Am. Chem. Soc., 146, 988, 10.1021/jacs.3c11637 · DOI
  36. Monie, 2022, Divergent aminolysis approach for constructing recyclable self-blown nonisocyanate polyurethane foams, ACS Macro Lett., 11, 236, 10.1021/acsmacrolett.1c00793 · DOI · Paper page
  37. Makarov, 2025, Advancing non-isocyanate polyurethane foams: exo -vinylene cyclic carbonate–amine chemistry enabling room-temperature reactivity and fast self-blowing, Macromolecules, 58, 1673, 10.1021/acs.macromol.4c02894 · DOI
  38. Bourguignon, 2025, Fast, catalyst-free room temperature production of isocyanate-free polyurethane foams using aromatic thiols, Polym. Chem., 16, 192, 10.1039/D4PY00971A · DOI
  39. Chen, 2024, Biobased, catalyst-free non-isocyanate polythiourethane foams: Highly dynamic nature affords fast reprocessability, extrudability and refoamability, Chem. Eng. J., 496, 10.1016/j.cej.2024.154035 · DOI
  40. Purwanto, 2024, Biobased, reprocessable, self-blown non-isocyanate polyurethane foams: Influence of blowing agent structure and functionality, Eur. Polym. J., 206, 10.1016/j.eurpolymj.2024.112775 · DOI
  41. Wang, 2024, Self-blowing non-isocyanate polyurethane foams from cyclic carbonate linseed oil, ACS Sustainable Resour Manage, 1, 462, 10.1021/acssusresmgt.3c00103 · DOI
  42. Sternberg, 2020, Materials for the biorefinery: high bio-content, shape memory Kraft lignin-derived non-isocyanate polyurethane foams using a non-toxic protocol, Green Chem., 22, 6922, 10.1039/D0GC01659D · DOI
  43. Ghasemlou, 2019, Bio-based routes to synthesize cyclic carbonates and polyamines precursors of non-isocyanate polyurethanes: A review, Eur. Polym. J., 118, 668, 10.1016/j.eurpolymj.2019.06.032 · DOI
  44. Trojanowska, 2024, Valorization of waste biomass for the fabrication of isocyanate-free polyurethane foams, Green Chem., 26, 8383, 10.1039/D4GC01547A · DOI
  45. Bakkali-Hassani, 2023, Polyhydroxyurethane covalent adaptable networks: looking for suitable catalysts, Polym. Chem., 14, 3610, 10.1039/D3PY00579H · DOI
  46. Chen, 2017, Reprocessable polyhydroxyurethane networks exhibiting full property recovery and concurrent associative and dissociative dynamic chemistry: Via transcarbamoylation and reversible cyclic carbonate aminolysis, Polym. Chem., 8, 6349, 10.1039/C7PY01160A · DOI
  47. Wang, 2024, Reprocessable, self-healing, and creep-resistant covalent adaptable network made from chain-growth monomers with dynamic covalent thionourethane and disulfide cross-links, ACS Macro. Lett., 13, 1147, 10.1021/acsmacrolett.4c00391 · DOI
  48. Chen, 2024, Non-isocyanate polythiourethane network from biowaste: achieving circularity via multidimensional chemical recycling with valuable small-molecule recovery and reprocessability by understanding the dynamic chemistry, Macromolecules, 57, 490, 10.1021/acs.macromol.3c01941 · DOI
  49. Pronoitis, 2022, Structurally diverse and recyclable isocyanate-free polyurethane networks from CO2-derived cyclic carbonates, ACS Sustain Chem Eng, 10, 2522, 10.1021/acssuschemeng.1c08530 · DOI
  50. Fortman, 2018, Rapidly reprocessable cross-linked polyhydroxyurethanes based on disulfide exchange, ACS Macro Lett., 7, 1226, 10.1021/acsmacrolett.8b00667 · DOI
  51. Li, 2020, Covalent adaptive networks for enhanced adhesion: exploiting disulfide dynamic chemistry and annealing during application, ACS Appl. Polym. Mater., 2, 4658, 10.1021/acsapm.0c00720 · DOI
  52. Chen, 2023, Biobased, reprocessable non-isocyanate polythiourethane networks with thionourethane and disulfide cross-links: comparison with polyhydroxyurethane network analogues, Macromolecules, 56, 3687, 10.1021/acs.macromol.3c00220 · DOI
  53. Panchireddy, 2017, Reinforced poly(hydroxyurethane) thermosets as high performance adhesives for aluminum substrates, Polym. Chem., 8, 5897, 10.1039/C7PY01209H · DOI
  54. Alferiev, 2005, A novel mercapto-bisphosphonate as an efficient anticalcification agent for bioprosthetic tissues, J. Organomet. Chem., 690, 2543, 10.1016/j.jorganchem.2004.10.011 · DOI
  55. Jayson, 1967, The radiation chemistry of cystamine sulphate, J. Chem. Soc. B, 944, 10.1039/j29670000944 · DOI
  56. Fortman, 2017, Structural effects on the reprocessability and stress relaxation of crosslinked polyhydroxyurethanes, J. Appl. Polym. Sci., 134, 44984, 10.1002/app.44984 · DOI
  57. Monie, 2024, The Multifaceted role of water as an accelerator for the preparation of isocyanate-free polyurethane thermosets, Macromolecules, 57, 8877
  58. Van Lijsebetten, 2022, Characterising different molecular landscapes in dynamic covalent networks, Chem. Sci., 13, 12865, 10.1039/D2SC05528G · DOI
  59. Deng, 2012, Dynamic hydrogels with an environmental adaptive self-healing ability and dual responsive Sol-Gel transitions, ACS Macro Lett., 1, 275, 10.1021/mz200195n · DOI
  60. Luo, 2018, Chemomechanics in the moisture-induced malleability of polyimine-based covalent adaptable networks, Macromolecules, 51, 9825, 10.1021/acs.macromol.8b02046 · DOI
  61. Taynton, 2014, Heat- or water-driven malleability in a highly recyclable covalent network polymer, Adv. Mater., 26, 3938, 10.1002/adma.201400317 · DOI · Paper page
  62. Sen Choong, 2021, Biobased nonisocyanate polyurethanes as recyclable and intrinsic self-healing coating with triple healing sites, ACS Macro Lett., 10, 635, 10.1021/acsmacrolett.1c00163 · DOI
  63. Panchireddy, 2018, Bio-based poly(hydroxyurethane) glues for metal substrates, Polym. Chem., 9, 2650, 10.1039/C8PY00281A · DOI
  64. Panchireddy, 2018, Catechol containing polyhydroxyurethanes as high-performance coatings and adhesives, ACS Sustain. Chem. Eng., 6, 14936, 10.1021/acssuschemeng.8b03429 · DOI
  65. Gomez-Lopez, 2021, Poly(hydroxyurethane) adhesives and coatings: state-of-the-art and future directions, ACS Sustain. Chem. Eng., 9, 9541, 10.1021/acssuschemeng.1c02558 · DOI
  66. Matos-Pérez, 2012, Polymer composition and substrate influences on the adhesive bonding of a biomimetic, cross-linking polymer, J. Am. Chem. Soc., 134, 9498, 10.1021/ja303369p · DOI
  67. Michal, 2016, Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer, ACS Appl. Mater. Interfaces, 8, 11041, 10.1021/acsami.6b01251 · DOI
  68. Canadell, 2011, Self-healing materials based on disulfide links, Macromolecules, 44, 2536, 10.1021/ma2001492 · DOI
  69. Imbernon, 2015, Chemically crosslinked yet reprocessable epoxidized natural rubber via thermo-activated disulfide rearrangements, Polym. Chem., 6, 4271, 10.1039/C5PY00459D · DOI
  70. Azcune, 2016, Aromatic disulfide crosslinks in polymer systems: Self-healing, reprocessability, recyclability and more, Eur. Polym. J., 84, 147, 10.1016/j.eurpolymj.2016.09.023 · DOI
  71. Verdugo, 2024, A biobased epoxy vitrimer with dual relaxation mechanism: A promising material for renewable, reusable, and recyclable adhesives and composites, ACS Sustain. Chem. Eng., 12, 5965, 10.1021/acssuschemeng.4c00205 · DOI
  72. S. Ebnesajjad, A.H. Landrock, Characteristics of Adhesive Materials, in: S. Ebnesajjad, A. H. Landrock (Eds.), Adhesives Technology Handbook, Elsevier, Amsterdam, 2015: pp. 84–159. https://doi.org/10.1016/B978-0-323-35595-7.00005-X. · DOI
  73. Van Lijsebetten, 2022, A highly dynamic covalent polymer network without creep: mission impossible?, Angew. Chem. Int. Ed., 61, 10.1002/anie.202210405 · DOI
  74. Bin Rusayyis, 2021, Reprocessable covalent adaptable networks with excellent elevated-temperature creep resistance: facilitation by dynamic, dissociative bis(hindered amino) disulfide bonds, Polym. Chem., 12, 2760, 10.1039/D1PY00187F · DOI
  75. Yi, 2020, The bonding between glass and metal, Int. J. Adv. Manuf. Technol., 111, 963, 10.1007/s00170-020-06018-x · DOI
  76. Overend, 2011, The selection and performance of adhesives for a steel–glass connection, Int. J. Adhes Adhes, 31, 587, 10.1016/j.ijadhadh.2011.06.001 · DOI
  77. Pereira, 2010, Analysis of manufacturing parameters on the shear strength of aluminium adhesive single-lap joints, J Mater Process Technol, 210, 610, 10.1016/j.jmatprotec.2009.11.006 · DOI
  78. G. Critchlow, Surface Treatments, in: L.F.M. da Silva, A. Öchsner, R.D. Adams (Eds)., Handbook of Adhesion Technology, in Springer Berlin Heidelberg, Berlin, Heidelberg, 2011: pp. 119-146. https://doi.org/10.1007/978-3-642-01169-6. · DOI
  79. Bao, 2023, Chemically recyclable supramolecular thermosets toward strong and reusable hot-melt adhesives, Macromolecules, 56, 6633, 10.1021/acs.macromol.3c01063 · DOI
  80. Tian, 2022, Applications of adhesives in textiles: A review, Eur. Polym. J., 167, 10.1016/j.eurpolymj.2022.111089 · DOI
  81. Rahman, 2021, Design of tough adhesive from commodity thermoplastics through dynamic crosslinking, Sci. Adv., 7, 10.1126/sciadv.abk2451 · DOI

Metadata

Authors
Lechuga-Islas, V. D., Gillissen, E., Bourguignon, M., Grignard, B., & Detrembleur, C.
Affiliations
University of Liège (BE)
Corresponding author
  • Grignard, Bruno
  • Detrembleur, Christophe
Venue
Chemical Engineering Journal
Publisher
Elsevier BV
Published
2025-07
Volume
516
Pages
163998
ISSN
1385-8947 (ISSN-L)
OpenAlex
W4410529874
Cited by
24
References
83
Citations by year
2026: 18 · 2025: 6
FWCI
5.57
Type
journal article
Language
en
Open access
Locations
  • Chemical Engineering Journal (publishedVersion)
  • ChemRxiv (acceptedVersion, cc-by-nc-nd)
  • ORBi (University of Liège) (submittedVersion, other-oa)
Funders
  • Fund for Scientific Research
  • Région wallonne
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Foaming and Composites
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Keywords
foam recycling, dynamic disulfide bonds, cystamine, adhesive recycling, lap shear strength, polyhydroxyurethanes

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review