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Built-in electric field induced CeO2/Ti3C2-MXene Schottky-junction for coupled photocatalytic tetracycline degradation and CO2 reduction
Abstract
Abstract Ti3C2-MXene, which exhibits excellent electronic conductivity and optical properties, has been identified as a promising noble-metal-free co-catalyst for the development of efficient photocatalysts for environmental remediation. Herein, CeO2/Ti3C2-MXene hybrids were prepared by the in-situ growth of cube-like CeO2 using ultrathin Ti3C2-MXene nanosheets as a two-dimensional platform via a simple hydrothermal route. Upon exposure to solar light, the CeO2/Ti3C2-MXene hybrid with the optimal ratio of Ti3C2-MXene exhibited enhanced performance in photocatalytic tetracycline degradation and CO2 reduction, with activities 6.3 and 1.5 times greater than those of pristine CeO2, respectively. The improved activity of CeO2/Ti3C2-MXene was attributed to the Schottky junction induced by the built-in electric field between CeO2 and Ti3C2-MXene, which drives the photogenerated electrons from CeO2 to Ti3C2-MXene and expedites the segregation of the electrons and holes. This work may shed light on the careful design of novel Schottky junctions utilizing noble-metal free Ti3C2-MXene as co-catalysts for building efficient photocatalytic systems enacted in pollutant degradation and energy conversion.
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Cites
Yang, Y., Zeng, Z., Zhang, C., Huang, D., Zeng, G., Xiao, R., Lai, C., Zhou, C., Guo, H., Xue, W., et al. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.05.093 · Cited by 691
Cited by
A Review on MXene Synthesis, Stability, and Photocatalytic Applications
Murali, G., Reddy Modigunta, J. K., Park, Y. H., Lee, J.-H., Rawal, J., Lee, S.-Y., In, I., & Park, S.-J. (2022) · ACS Nano · doi:10.1021/acsnano.2c04750 · Cited by 668
MXenes as emerging nanomaterials in water purification and environmental remediation
Yu, S., Tang, H., Zhang, D., Wang, S., Qiu, M., Song, G., Fu, D., Hu, B., & Wang, X. (2022) · Science of The Total Environment · doi:10.1016/j.scitotenv.2021.152280 · Cited by 445
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Metadata
- Authors
- Shen, J., Shen, J., Zhang, W., Yu, X., Tang, H., Zhang, M., Zulfiqar, & Liu, Q.
- Venue
- Ceramics International
- Publisher
- Elsevier BV
- Published
- 2019-12
- Volume
- 45
- Issue
- 18
- Pages
- 24146-24153
- ISSN
- 0272-8842 (ISSN-L)
- OpenAlex
- W2969432033
- Cited by
- 221
- References
- 1
- FWCI
- 5.15
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shen, J., Shen, J., Zhang, W., Yu, X., Tang, H., Zhang, M., Zulfiqar, & Liu, Q. (2019). Built-in electric field induced CeO2/Ti3C2-MXene Schottky-junction for coupled photocatalytic tetracycline degradation and CO2 reduction. Ceramics International. https://doi.org/10.1016/j.ceramint.2019.08.123
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