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Built-in electric field induced CeO2/Ti3C2-MXene Schottky-junction for coupled photocatalytic tetracycline degradation and CO2 reduction

Shen, Jiyou, Shen, Jun, Zhang, Wenjing, Yu, Xiaohui, Tang, Hua, Zhang, Mingyi, Zulfiqar, Liu, Qinqin·2019·Ceramics International

Abstract

Abstract Ti3C2-MXene, which exhibits excellent electronic conductivity and optical properties, has been identified as a promising noble-metal-free co-catalyst for the development of efficient photocatalysts for environmental remediation. Herein, CeO2/Ti3C2-MXene hybrids were prepared by the in-situ growth of cube-like CeO2 using ultrathin Ti3C2-MXene nanosheets as a two-dimensional platform via a simple hydrothermal route. Upon exposure to solar light, the CeO2/Ti3C2-MXene hybrid with the optimal ratio of Ti3C2-MXene exhibited enhanced performance in photocatalytic tetracycline degradation and CO2 reduction, with activities 6.3 and 1.5 times greater than those of pristine CeO2, respectively. The improved activity of CeO2/Ti3C2-MXene was attributed to the Schottky junction induced by the built-in electric field between CeO2 and Ti3C2-MXene, which drives the photogenerated electrons from CeO2 to Ti3C2-MXene and expedites the segregation of the electrons and holes. This work may shed light on the careful design of novel Schottky junctions utilizing noble-metal free Ti3C2-MXene as co-catalysts for building efficient photocatalytic systems enacted in pollutant degradation and energy conversion.

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Metadata

Authors
Shen, J., Shen, J., Zhang, W., Yu, X., Tang, H., Zhang, M., Zulfiqar, & Liu, Q.
Venue
Ceramics International
Publisher
Elsevier BV
Published
2019-12
Volume
45
Issue
18
Pages
24146-24153
ISSN
0272-8842 (ISSN-L)
OpenAlex
W2969432033
Cited by
221
References
1
FWCI
5.15
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Built-in electric field induced CeO2/Ti3C2-MXene Schottky-junction for coupled photocatalytic tetracycline degradation and CO2 reduction. https://app.cochat.ai/papers/10.1016/j.ceramint.2019.08.123
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Shen, J., Shen, J., Zhang, W., Yu, X., Tang, H., Zhang, M., Zulfiqar, & Liu, Q. (2019). Built-in electric field induced CeO2/Ti3C2-MXene Schottky-junction for coupled photocatalytic tetracycline degradation and CO2 reduction. Ceramics International. https://doi.org/10.1016/j.ceramint.2019.08.123

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