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Siderite acid fractionation factors for sealed and open vessel digestions at 70 °C and 100 °C
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Specific acid fractionation factors for different analytical methods and reaction temperatures have been derived empirically.
“but specific acid fractionation factors for different analytical methods and reaction temperatures have also been derived empirically. 18 , 32 , 33”
From Improving the routine analysis of siderite for δ 13 C and δ 18 O in environmental change research (2023) · cites this paper as [33]
The interlaboratory comparison of ETH test siderites was undertaken on a retrospective basis and the BGS and UoL measurements were completed approximately 12 months after the original ETH data had been published.
“The interlaboratory comparison of ETH test siderites was undertaken on a retrospective basis and the BGS and UoL measurements were completed approximately 12 months after the original ETH data had been published. 33”
From Improving the routine analysis of siderite for δ 13 C and δ 18 O in environmental change research (2023) · cites this paper as [33]
Three published studies report estimates for the temperature‐dependent fractionation of oxygen isotopes during the production of CO2 by reaction of siderite with anhydrous phosphoric acid between 25°C and 150°C.
“Three published studies report estimates for the temperature‐dependent fractionation of oxygen isotopes during the production of CO2 by reaction of siderite with anhydrous phosphoric acid between 25°C and 150°C. 18 , 29 , 33”
From Improving the routine analysis of siderite for δ 13 C and δ 18 O in environmental change research (2023) · cites this paper as [33]
Changes in the δ18O value of CO2 with reaction progress have been reported for calcite, dolomite, and siderite.
“Changes in the δ18O value of CO2 with reaction progress have been reported for calcite, dolomite, and siderite. 26 , 33 , 39 , 58”
From Improving the routine analysis of siderite for δ 13 C and δ 18 O in environmental change research (2023) · cites this paper as [33]
Citations
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References 30 · Cited by 17
Research works printed but not linked: 15
- Boschetti, 2005, Continuous-flow δ18O measurements: new approach to standardization, high-temperature thermodynamic and sulfate analysis, Rapid Commun. Mass Spectrom., 19, 3007, 10.1002/rcm.2161 · DOI
- Bottinga, 1968, Oxygen isotope fractionation between CO2 and water, and the isotopic composition of marine atmospheric CO2, Earth Planet. Sci. Lett., 5, 285, 10.1016/S0012-821X(68)80054-8 · DOI
- Kele, 2015, Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: a study of travertines and tufas in the 6–95°C temperature range, Geochim. Cosmochim. Acta, 168, 172, 10.1016/j.gca.2015.06.032 · DOI · Paper page
- Kim, 2015, Normalization of stable isotope data for carbonate minerals: implementation of IUPAC guidelines, Geochim. Cosmochim. Acta, 158, 276, 10.1016/j.gca.2015.02.011 · DOI · Paper page
- Ludvigson, 1998, Meteoric sphaerosiderite lines and their use for paleohydrology and paleoclimatology, Geology, 26, 1039, 10.1130/0091-7613(1998)026<1039:MSLATU>2.3.CO;2 · DOI
- McCrea, 1950, On the isotope chemistry of carbonates and a paleotemperature scale, J. Chem. Phys., 18, 849, 10.1063/1.1747785 · DOI · Paper page
- Müller, 2016, Clumped isotope fractionation during phosphoric acid digestion of carbonates at 70°C, Chem. Geol.
- Poulsen, 2007, General circulation model simulation of the δ18O content of continental precipitation in the middle Cretaceous: a model-proxy comparison, Geology, 35, 199, 10.1130/G23343A.1 · DOI
- Suarez, 2009, Isotopic composition of low-latitude paleoprecipitation during the early Cretaceous, Bull. Geol. Soc. Am., 121, 1584, 10.1130/B26453.1 · DOI
- Suarez, 2011, Quantification of a greenhouse hydrologic cycle from equatorial to polar latitudes: the mid-Cretaceous water bearer revisited, Palaeogeogr. Palaeoclimatol. Palaeoecol., 307, 301, 10.1016/j.palaeo.2011.05.027 · DOI
- Ufnar, 2002, The mid-Cretaceous water bearer: isotope mass balance quantification of the Albian hydrologic cycle, Palaeogeogr. Palaeoclimatol. Palaeoecol., 188, 51, 10.1016/S0031-0182(02)00530-8 · DOI
- Wachter, 1985, Exchange of oxygen isotopes in carbon dioxide-phosphoric [correction of phosphoric] acid systems, Isot. Geosci., 52, 365, 10.1016/0168-9622(85)90046-6 · DOI · Paper page
- Wacker, 2013, Clumped isotope analysis of carbonates: comparison of two different acid digestion techniques, Rapid Commun. Mass Spectrom., 27, 1631, 10.1002/rcm.6609 · DOI · Paper page
- White, 2001, Middle K greenhouse hydrologic cycle of North America, Geology, 29, 363, 10.1130/0091-7613(2001)029<0363:MCGHCO>2.0.CO;2 · DOI · Paper page
- Wiesli, 2004, Experimental determination of Fe isotope fractionation between aqueous Fe(II), siderite and green rust in abiotic systems, Chem. Geol., 211, 343, 10.1016/j.chemgeo.2004.07.002 · DOI
Metadata
- Authors
- Fernandez, A., van Dijk, J., Müller, I. A., & Bernasconi, S. M.
- Affiliations
- ETH Zurich (CH)
- Venue
- Chemical Geology
- Publisher
- Elsevier BV
- Published
- 2016-12
- Volume
- 444
- Pages
- 180-186
- ISSN
- 0009-2541 (ISSN-L)
- OpenAlex
- W2531278255
- Cited by
- 17
- References
- 30
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 2 · 2022: 5 · 2021: 1 · 2020: 1 · 2019: 2 · 2017: 2 · 2016: 1
- FWCI
- 1.39
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Chemical Geology (acceptedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (acceptedVersion)
- Funders
- Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (160046, 156408)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- siderite, oxygen isotope fractionation, fractionation factor, acid digestion, temperature dependence, clumped isotopes, carbonate minerals, paleoenvironmental reconstruction
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