Cited by 87Advanced oxidation water treatmentWater Treatment and DisinfectionAdvanced Photocatalysis Techniques

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Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification

Abstract

The degradation of acetaminophen (ACM) was comparatively studied by UV/chlorine and UV/H 2 O 2 systems. An apparent reduction in the removal rate was observed above the optimum pH levels of 7.0 and 3.0 in UV/chlorine and UV/H 2 O 2 processes, respectively. The relative contribution of each oxidizing agent in ACM removal using the two advanced oxidation processes (AOPs) was evaluated. Even though hydroxyl radicals, with the contribution percentage of 90.1%, were determined as the primary oxidizing species in ACM removal using the UV/H 2 O 2 process, reactive chlorine species (RCS), with 43.8% of contribution percentage, were also found to play a pivotal role in ACM removal using the UV/chlorine process. For instance, dichlorine radical (Cl 2•-) showed an acceptable contribution percentage of 32.2% in the degradation of ACM by the UV/chlorine process. The rate of ACM degradation significantly rose to 99.9% and 75.6%, as higher amounts of oxidants were used in the UV/chlorine and UV/H 2 O 2 processes, respectively, within 25 min. The introduction of HCO 3- ions and humic acid remarkably decreased the rate of ACM degradation in both techniques used in this study. The presence of NO 3- and Cl- ions did not considerably affect the removal rate in the UV/chlorine process. The acute toxicity analysis revealed that a more pronounced reduction in the ACM solution toxicity could be achieved by the UV/H 2 O 2 process compared to the UV/chlorine process, which should be ascribed to the formation of chlorinated products in the UV/chlorine treatment. Eventually, plausible oxidation pathways were proposed for each process.

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Crossref · 10.1016/j.chemosphere.2021.131455

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Research works printed but not linked: 2

  1. Dao, 2018, Degradation of paracetamol by an UV/chlorine advanced oxidation process: influencing factors, Factorial Design, and Intermediates Identification, 15, 2637
  2. Durand-Niconoff, 2012, vol. 112, 3570

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Metadata

Authors
Ghanbari, F., Yaghoot-Nezhad, A., Wacławek, S., Lin, K.-Y. A., Rodríguez-Chueca, J., & Mehdipour, F.
Affiliations
  • Abadan University of Medical Sciences (IR)
  • Petroleum University of Technology (IR)
  • Technical University of Liberec (CZ)
  • National Chung Hsing University (TW)
  • Shahid Beheshti University (IR)
Corresponding author
  • Ghanbari, Farshid
  • Wacławek, Stanisław
  • Lin, Kun-Yi Andrew
Venue
Chemosphere
Publisher
Elsevier BV
Published
2021-12
Volume
285
Pages
131455
ISSN
0045-6535 (ISSN-L)
OpenAlex
W3179697724
Cited by
87
References
60
Citations by year
2026: 6 · 2025: 15 · 2024: 14 · 2023: 25 · 2022: 19 · 2021: 8
FWCI
4.92
Type
journal article
Language
en
Open access
closed
Locations
  • Chemosphere (publishedVersion)
  • PubMed (publishedVersion)
  • Hispana (acceptedVersion)
  • UPM Digital Archive (Technical University of Madrid) (submittedVersion)
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Water Treatment and Disinfection
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
Keywords
acetaminophen degradation, UV/chlorine process, UV/H2O2 process, advanced oxidation processes, hydroxyl radicals, reactive chlorine species, degradation kinetics, acute toxicity, chlorination by-products, humic acid inhibition, bicarbonate inhibition, oxidation pathways, pharmaceutical removal from water
MeSH terms
Acetaminophen, Chlorine, Feasibility Studies, Hydrogen Peroxide, Kinetics, Ultraviolet Rays, Water Pollutants, Chemical, Process Assessment, Health Care, Water Purification

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Ghanbari, F., Yaghoot-Nezhad, A., Wacławek, S., Lin, K.-Y. A., Rodríguez-Chueca, J., & Mehdipour, F. (2021). Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification. Chemosphere. https://doi.org/10.1016/j.chemosphere.2021.131455