The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Electrolyzer Design for Flexible Decoupled Water Splitting and Organic Upgrading with Electron Reservoirs
Open accessAbstract
Summary Conventional water-splitting electrolysis drives the H 2 and O 2 evolution reactions (HER and OER, respectively) simultaneously with large voltage inputs. Herein, two inexpensive iron complexes as proton-independent electron reservoirs (ERs) are described for decoupled water electrolysis. (Ferrocenylmethyl)trimethylammonium chloride and Na 4 [Fe(CN) 6 ], which have proper redox potentials in aqueous media, are able to couple their oxidation with HER. The subsequent reduction of the oxidized ER + is then paired with OER. Both steps require much smaller voltage than that of direct water splitting. Nearly 100% Faradic efficiency and remarkable cycling stability were obtained for both ERs. Such decoupled water splitting could also be driven by photovoltaic cells with small photovoltages under sunlight irradiation. Furthermore, a two-step electrolysis of HER and the oxidation of 5-hydroxymethylfurfural mediated by Na 4 [Fe(CN) 6 ] was demonstrated under alkaline conditions, producing H 2 and 2,5-furandicarboxylic acid. This work presents a decoupled water electrolyzer design with great flexibility and safety advantages.
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Cites
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
You, B., Liu, X., Hu, G., Gul, S., Yano, J., Jiang, D.-E., & Sun, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06434 · Cited by 266
Self-citation
Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Self-citationYang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Water Electrolysis toward Elevated Temperature: Advances, Challenges and Frontiers
Zhang, W., Liu, M., Gu, X., Shi, Y., Deng, Z., & Cai, N. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00573 · Cited by 441
Roadmap and Direction toward High-Performance MoS 2 Hydrogen Evolution Catalysts
Cao, Y. (2021) · ACS Nano · doi:10.1021/acsnano.1c01879 · Cited by 405
Photocatalytic and Photoelectrochemical Systems: Similarities and Differences
Wu, H., Tan, H. L., Toe, C. Y., Scott, J., Wang, L., Amal, R., & Ng, Y. H. (2020) · Advanced Materials · doi:10.1002/adma.201904717 · Cited by 394
Metadata
- Authors
- Li, W., Jiang, N., Hu, B., Liu, X., Song, F., Han, G., Jordan, T. J., Hanson, T. B., Liu, T. L., & Sun, Y.
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2018-03
- Volume
- 4
- Issue
- 3
- Pages
- 637-649
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W2787385842
- Cited by
- 174
- References
- 2
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- bronze
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- The paper
- Li, W., Jiang, N., Hu, B., Liu, X., Song, F., Han, G., Jordan, T. J., Hanson, T. B., Liu, T. L., & Sun, Y. (2018). Electrolyzer Design for Flexible Decoupled Water Splitting and Organic Upgrading with Electron Reservoirs. Chem. https://doi.org/10.1016/j.chempr.2017.12.019
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