The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Intermediate Modulation on Noble Metal Hybridized to 2D Metal-Organic Framework for Accelerated Water Electrocatalysis
Open accessAbstract
Summary The rational modulation of reaction intermediates is critical to achieving high-performance heterogeneous catalysis. However, practical realization remains challenging. Using water electrocatalysis as a model reaction, we report an interfacial-bond-induced intermediate modulation to accelerate the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by hybridizing a 2D nickel metal-organic framework (MOF) and Pt nanocrystals into a heterostructure. The design is initially verified via theoretical calculations, indicating charge relocation on newly formed Ni–O–Pt interfacial bonds for increased OH* adsorption energy together with reduced H* adsorption energy. Experimental findings confirm the formation of the Ni–O–Pt bonds, which electronically modify the heterostructure to increase electron density for Pt and the high-energy Ni 3d state for the MOF, optimizing the adsorption for H* and OH*, respectively. This hybridized material delivered HER activity of 7.92 mA μg−1 Pt, which is among the best reported for alkaline electrocatalysts, and an improved OER activity.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Self-citationEnhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction
Mahmood, J., Li, F., Jung, S.-M., Okyay, M. S., Ahmad, I., Kim, S.-J., Park, N., Jeong, H. Y., & Baek, J.-B. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2016.304 · Cited by 1,685
High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Jaroniec, M., & Qiao, S.-Z. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11291 · Cited by 1,110
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(2020) · doi:10.1038/s41467-020-19277-9 · Cited by 690
Deng, L., Hu, F., Ma, M., Huang, S., Xiong, Y., Chen, H., Li, L., & Peng, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202110374 · Cited by 331
Liu, D., Ai, H., Li, J., Fang, M., Chen, M., Liu, D., Du, X., Zhou, P., Li, F., Lo, K. H., et al. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002464 · Cited by 303
Li, C.-F., Shuai, T.-Y., Zheng, L.-R., Tang, H.-B., Zhao, J.-W., & Li, G.-R. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.138618 · Cited by 149
Atomically Dispersed MoO x on Rhodium Metallene Boosts Electrocatalyzed Alkaline Hydrogen Evolution
Wu, J., Fan, J., Zhao, X., Wang, Y., Wang, D., Liu, H., Gu, L., Zhang, Q., Zheng, L., Singh, D. J., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202207512 · Cited by 123
Metadata
- Authors
- Guo, C., Jiao, Y., Zheng, Y., Luo, J., Davey, K., & Qiao, S.-Z.
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2019-09
- Volume
- 5
- Issue
- 9
- Pages
- 2429-2441
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W2959533710
- Cited by
- 208
- References
- 6
- FWCI
- 5.72
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Guo, C., Jiao, Y., Zheng, Y., Luo, J., Davey, K., & Qiao, S.-Z. (2019). Intermediate Modulation on Noble Metal Hybridized to 2D Metal-Organic Framework for Accelerated Water Electrocatalysis. Chem. https://doi.org/10.1016/j.chempr.2019.06.016
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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