Cited by 97Polymer composites and self-healingAdvanced Materials and MechanicsPolymer crystallization and properties

The role of cellulose nanocrystals in the improvement of the shape-memory properties of castor oil-based segmented thermoplastic polyurethanes

Saralegi, Ainara, Gonzalez, Maria Luz, Valea, Angel, Eceiza, Arantxa, Corcuera, Maria Angeles·2014·Composites Science and Technology

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Crossref · 10.1016/j.compscitech.2013.12.001

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  • Microphase separation was responsible for two main transitions: soft and hard phase melting temperatures.

    “This was responsible for the presence of two main transitions: soft and hard phase melting temperatures.”
  • CNCs were incorporated as a hard segment in PU bionanocomposites to improve their mechanical properties.

    “CNCs were incorporated as a hard segment in PU bionanocomposites in order to improve their mechanical properties [187].”
  • Thermodynamic incompatibility between soft and hard segments resulted in microphase separation of PU/CNCs bionanocomposites.

    “As a result of the thermodynamic incompatibility between both segments, microphase separation of PU/CNCs bionanocomposites was obtained.”
  • Thermally activated SMPs are formed by two active phases having a thermal transition at a determined temperature (Ttrans), the fixity phase and the switch phase, which can be covalently attached during the synthesis.

    “Thermally activated SMPs are formed by two active phases having a thermal transition at a determined temperature (Ttrans) [12], the fixity phase and the switch phase [13, 14], which can be covalently attached during the synthesis [15, 16].”

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References 38 · Cited by 97

Authors
Saralegi, A., Gonzalez, M. L., Valea, A., Eceiza, A., & Corcuera, M. A.
Affiliations
University of the Basque Country (ES)
Corresponding author
Eceiza, Arantxa
Venue
Composites Science and Technology
Publisher
Elsevier BV
Published
2014-02
Volume
92
Pages
27-33
ISSN
0266-3538 (ISSN-L)
OpenAlex
W1976369846
Cited by
97
References
38
Citations by year
2026: 2 · 2025: 3 · 2024: 4 · 2023: 4 · 2022: 6 · 2021: 6 · 2020: 7 · 2019: 8 · 2018: 14 · 2017: 15 · 2016: 11 · 2015: 10 · 2014: 7
FWCI
6.74
Type
journal article
Language
en
Open access
closed
Locations
  • Composites Science and Technology (publishedVersion)
  • TECNALIA Publications (Fundación TECNALIA Research & Innovation) (submittedVersion)
Funders
Eusko Jaurlaritza
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Keywords
cellulose nanocrystals, shape memory polymers, castor oil, in situ polymerization, microphase separation, crystallinity, shape recovery, renewable raw materials

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