The role of cellulose nanocrystals in the improvement of the shape-memory properties of castor oil-based segmented thermoplastic polyurethanes
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Microphase separation was responsible for two main transitions: soft and hard phase melting temperatures.
“This was responsible for the presence of two main transitions: soft and hard phase melting temperatures.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [187]
CNCs were incorporated as a hard segment in PU bionanocomposites to improve their mechanical properties.
“CNCs were incorporated as a hard segment in PU bionanocomposites in order to improve their mechanical properties [187].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [187]
Thermodynamic incompatibility between soft and hard segments resulted in microphase separation of PU/CNCs bionanocomposites.
“As a result of the thermodynamic incompatibility between both segments, microphase separation of PU/CNCs bionanocomposites was obtained.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [187]
Thermally activated SMPs are formed by two active phases having a thermal transition at a determined temperature (Ttrans), the fixity phase and the switch phase, which can be covalently attached during the synthesis.
“Thermally activated SMPs are formed by two active phases having a thermal transition at a determined temperature (Ttrans) [12], the fixity phase and the switch phase [13, 14], which can be covalently attached during the synthesis [15, 16].”
From Biodegradable poly(ester-urethane) incorporated with catechin with shape memory and antioxidant activity for food packaging (2017) · cites this paper as [12]
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References 38 · Cited by 97
- Authors
- Saralegi, A., Gonzalez, M. L., Valea, A., Eceiza, A., & Corcuera, M. A.
- Affiliations
- University of the Basque Country (ES)
- Corresponding author
- Eceiza, Arantxa
- Venue
- Composites Science and Technology
- Publisher
- Elsevier BV
- Published
- 2014-02
- Volume
- 92
- Pages
- 27-33
- ISSN
- 0266-3538 (ISSN-L)
- OpenAlex
- W1976369846
- Cited by
- 97
- References
- 38
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 4 · 2023: 4 · 2022: 6 · 2021: 6 · 2020: 7 · 2019: 8 · 2018: 14 · 2017: 15 · 2016: 11 · 2015: 10 · 2014: 7
- FWCI
- 6.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Composites Science and Technology (publishedVersion)
- TECNALIA Publications (Fundación TECNALIA Research & Innovation) (submittedVersion)
- Funders
- Eusko Jaurlaritza
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- cellulose nanocrystals, shape memory polymers, castor oil, in situ polymerization, microphase separation, crystallinity, shape recovery, renewable raw materials
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