The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Evolution of hydrogen at dissolving magnesium surfaces
Open accessAbstract
The origin of hydrogen evolved at dissolving magnesium surfaces, including those subjected to anodic polarisation, remains a topical issue. In this work, a critical appraisal of existing theories is presented, along with data from simultaneous polarisation and hydrogen collection tests. The observations invalidate mechanisms invoking the presence of univalent Mg+. A combined experimental and thermodynamic analysis suggests that the ability of magnesium to support the cathodic reaction is enhanced during dissolution as the result of an increase in the exchange current density for the hydrogen evolution reaction, This mechanism can also explain high rates of hydrogen evolution in aluminium pits.
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Cites
Electrochemical Methods: Fundamentals and Applications
Bard, A. J., & Faulkner, L. R. (1980) · Cited by 22,435
Electrochemical methods: Fundamentals and applications
Vondrák, J. (1983) · Surface Technology · doi:10.1016/0376-4583(83)90080-8 · Cited by 4,688
Baes, C. F., & Mesmer, R. E. (1976) · Medical Entomology and Zoology · Cited by 4,657
The anodic dissolution of magnesium in chloride and sulphate solutions
Song, G., Atrens, A., John, D. S., Wu, X., & Nairn, J. (1997) · Corrosion Science · doi:10.1016/s0010-938x(97)00090-5 · Cited by 890
Kirkland, N. T., Birbilis, N., & Staiger, M. P. (2012) · Acta Biomaterialia · doi:10.1016/j.actbio.2011.11.014 · Cited by 856
Self-citationThe electrochemical corrosion of pure magnesium in 1 N NaCl
Song, G., Atrens, A., Stjohn, D., Nairn, J., & Li, Y. (1997) · Corrosion Science · doi:10.1016/s0010-938x(96)00172-2 · Cited by 614
Hertz, G. (1999) · Zeitschrift für Physikalische Chemie · doi:10.1524/zpch.1999.212.part_2.233 · Cited by 425
Qiao, Z., Shi, Z., Hort, N., Zainal Abidin, N. I., & Atrens, A. (2012) · Corrosion Science · doi:10.1016/j.corsci.2012.04.030 · Cited by 199
The growth of 2-D pits in thin film aluminum
Frankel, G. S. (1990) · Corrosion Science · doi:10.1016/0010-938x(90)90199-f · Cited by 129
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Fundamentals and advances in magnesium alloy corrosion
Esmaily, M., Svensson, J. E., Fajardo, S., Birbilis, N., Frankel, G. S., Virtanen, S., Arrabal, R., Thomas, S., & Johansson, L. G. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.04.011 · Cited by 2,073
Self-citationKing, A. D., Birbilis, N., & Scully, J. R. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2013.12.124 · Cited by 640
Self-citationKovacevic, S., Ali, W., Mandal, T. K., Martínez-Pañeda, E., & LLorca, J. (2025) · Acta Biomaterialia · doi:10.1016/j.actbio.2025.03.034 · Cited by 31
Metadata
- Authors
- Frankel, G. S., Samaniego, A., & Birbilis, N.
- Venue
- Corrosion Science
- Publisher
- Elsevier BV
- Published
- 2013-05
- Volume
- 70
- Pages
- 104-111
- ISSN
- 0010-938X (ISSN-L)
- OpenAlex
- W2035037549
- Cited by
- 403
- References
- 9
- FWCI
- 14.02
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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