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Organometallic approach to the synthesis and surface reactivity of noble metal nanoparticles
Abstract
The use of organometallic precursors allows the synthesis in mild conditions of nanoparticles of uniform small size (1–3 nm) and of clean surface, which can be stabilized by polymers or ligands. These nano-objects display an interesting surface chemistry comparable to that of molecular species. This involves classical elementary steps of organometallic chemistry such as substitution and oxidative addition as well as ligand fluxionality. An overview of recent work in this field from our group will be presented including stabilization of metal nanoparticles by asymmetric ligands and preliminary catalytic attempts.
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Cited by
Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 689
Conductive nanomaterials for 2D and 3D printed flexible electronics
Kamyshny, A., & Magdassi, S. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00738a · Cited by 469
Transition‐metal nanoparticles: synthesis, stability and the leaching issue
Pachón, L. D., & Rothenberg, G. (2008) · Applied Organometallic Chemistry · doi:10.1002/aoc.1382 · Cited by 443
Datta, K. K. R., Reddy, B. V. S., Ariga, K., & Vinu, A. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001699 · Cited by 375
A Case for Enantioselective Allylic Alkylation Catalyzed by Palladium Nanoparticles
Jansat, S., Gómez, M., Philippot, K., Muller, G., Guiu, E., Claver, C., Castillón, S., & Chaudret, B. (2004) · Journal of the American Chemical Society · doi:10.1021/ja036132k · Cited by 274
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Metadata
- Authors
- Philippot, K., & Chaudret, B.
- Venue
- Comptes Rendus. Chimie
- Publisher
- MathDoc/Centre Mersenne
- Published
- 2003-08-01
- Volume
- 6
- Issue
- 8-10
- Pages
- 1019-1034
- ISSN
- 1631-0748 (ISSN-L)
- 1878-1543
- OpenAlex
- W1988373554
- Cited by
- 176
- References
- 0
- FWCI
- 3.76
- Type
- journal article
- Language
- en
- Open access
- closed
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