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Cited by 8Pesticide Residue Analysis and SafetyAnalytical chemistry methods developmentAgricultural safety and regulations

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Multivariate response surface methodology assisted modified QuEChERS method for the rapid determination of 39 pesticides and metabolites in medlar

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Zhuang, Ming, Yao, Wei, Han, Lijun, Bi, Yingying, Qiao, Chengkui, Lv, Xinru, Cao, Mengyuan, Xie, Hanzhong·2023·Ecotoxicology and Environmental Safety
DOI 10.1016/j.ecoenv.2023.115102
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Abstract

A modified QuEChERS method coupled with high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was established for residue analysis of 39 pollutants (34 commonly used multi-class pesticides and 5 metabolites) in medlar matrices (fresh, dried, and medlar juice). Samples were extracted using water with 0.1 % formic acid: acetonitrile (5: 10, v/v). The phase-out salts and five different cleanup sorbents (including N-propyl ethylenediamine (PSA), octadecyl silane bonded silica gel (C18), graphitized carbon black (GCB), Carbon nanofiber (C-Fiber) and MWCNTs) were investigated to improve the purification efficiency. The Box-Behnken Design (BBD) study was employed for an optimal solution of the volume of extraction solvent, phase-out salt, and the purification sorbents for the analytical method. The average recoveries of the target analytes in the three medlar matrices ranged from 70 % to 119 % with relative standard deviations (RSDs) of 1.0 %-19.9 %. Screening of market samples (fresh and dried medlars) collected from the major producing regions in China showed that 15 pesticides and metabolites were detected in the samples at concentrations of 0.01-2.22 mg/kg, and none of which exceeded the maximum residue limits (MRLs) set in China. The results showed that the risk of food safety by consumption of medlar products caused by the use of pesticides was low. The validated method could be used for rapid and accurate screening of multi-class multi-pesticide residue…

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Metadata

Authors
Zhuang, M., Yao, W., Han, L., Bi, Y., Qiao, C., Lv, X., Cao, M., & Xie, H.
Affiliations
  • China Agricultural University (CN)
  • Beijing Vocational College of Agriculture (CN)
  • Zhengzhou Fruit Research Institute (CN)
Corresponding author
Han, Lijun
ORCID
Venue
Ecotoxicology and Environmental Safety
Publisher
Elsevier BV
Published
2023-08
Volume
261
Pages
115102
ISSN
0147-6513 (ISSN-L)
DOI
10.1016/j.ecoenv.2023.115102
OpenAlex
W4380199627
Cited by
8
References
0
Citations by year
2025: 3 · 2024: 5
FWCI
1.16
Type
journal article
Language
en
Open access
Licence
Locations
  • Ecotoxicology and Environmental Safety (publishedVersion, cc-by-nc-nd)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Topics
  • Life Sciences › Agricultural and Biological Sciences › Food Science › Pesticide Residue Analysis and Safety
  • Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
  • Life Sciences › Agricultural and Biological Sciences › Food Science › Agricultural safety and regulations
Keywords
medlar, pesticide residues, pesticide metabolites, QuEChERS, Box-Behnken design, carbon nanotubes, food safety, maximum residue limits
MeSH terms
Chromatography, High Pressure Liquid, Pesticide Residues, Pesticides, Vegetables, Solid Phase Extraction, Tandem Mass Spectrometry

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