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Activated-phosphorus as new electrode material for Li-ion batteries
Open accessAbstract
An innovative concept of activation of electrode materials for Li-ion batteries is proposed through the preparation of carbon-phosphorus (P/C) composites. Carbon-encapsulated phosphorus composites can be successfully prepared via a simple route by the vaporization–condensation of red phosphorus onto mesoporous carbon. Surface area measurements and Raman spectroscopy were used for the characterization of the P/C composites, which were then tested as anode materials in Li-ion batteries showing enhanced electrochemical properties. In contrast to what is observed for pure unsupported phosphorus, Li storage in P/C composite occurs through the reversible formation of Li3P during the discharge process, as clearly evidenced by in situ XRD, leading to capacities greater than 900 mAh g−1 after 20 cycles.
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Cited by
An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries
Kim, Y., Park, Y., Choi, A., Choi, N., Kim, J., Lee, J., Ryu, J. H., Oh, S. M., & Lee, K. T. (2013) · Advanced Materials · doi:10.1002/adma.201204877 · Cited by 854
Li, W., Yang, Y., Zhang, G., & Zhang, Y.-W. (2015) · Nano Letters · doi:10.1021/nl504336h · Cited by 773
Negative electrodes for Na-ion batteries
Dahbi, M., Yabuuchi, N., Kubota, K., Tokiwa, K., & Komaba, S. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00826j · Cited by 623
Li, W., Yang, Z., Li, M., Jiang, Y., Wei, X., Zhong, X., Gu, L., & Yu, Y. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b03903 · Cited by 396
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
Metadata
- Authors
- Marino, C., Debenedetti, A., Fraisse, B., Favier, F., & Monconduit, L.
- Venue
- Electrochemistry Communications
- Publisher
- Elsevier BV
- Published
- 2011-04
- Volume
- 13
- Issue
- 4
- Pages
- 346-349
- ISSN
- 1388-2481 (ISSN-L)
- OpenAlex
- W2005022064
- Cited by
- 174
- References
- 0
- FWCI
- 5.12
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Marino, C., Debenedetti, A., Fraisse, B., Favier, F., & Monconduit, L. (2011). Activated-phosphorus as new electrode material for Li-ion batteries. Electrochemistry Communications. https://doi.org/10.1016/j.elecom.2011.01.021
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