The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Regulating Li deposition by constructing LiF-rich host for dendrite-free lithium metal anode
Abstract
Abstract Lithium (Li) metal anode is among the most promising anodes due to its high energy density. However, the long-standing issue of Li dendrites growth hinders the practical application of lithium metal batteries (LMBs) in portable electronics and electric vehicles. Engineering a dendrite-free Li metal anode is therefore critical for the development of long-life batteries. Here, an artificial LiF host with cuboid feature is constructed on Li metal surface by a facial one-step reaction of ammonium hydrogen difluoride (NH4HF2) with bare Li metal. During cycling, Li grows continuously from the bottom gaps to the top of the LiF host and finally cover the surface of the modified anode. Particularly, with the increasing of cycling capacity, the Li metal tend to deposit into scaly morphology which contributes to a dendrite-free anode. The as-obtained smooth Li anodes enabled stable cycling in working batteries with a low overpotential and a high Coulombic efficiency (CE) of 98.5% at the current density of 1 mA cm−2. This work provides a facile approach to prepare LiF-rich Li anode which paves the way to construct high-energy and safe LMBs.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Cited by
High‐Energy Lithium‐Ion Batteries: Recent Progress and a Promising Future in Applications
Xu, J., Cai, X., Cai, S., Shao, Y., Hu, C., Lu, S., & Ding, S. (2023) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12450 · Cited by 1,201
A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase
Tan, J., Matz, J., Dong, P., Shen, J., & Ye, M. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100046 · Cited by 1,019
Lithium metal anodes: Present and future
Wang, R., Cui, W., Chu, F., & Wu, F. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.12.024 · Cited by 544
Self-citationFluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition
Pathak, R., Chen, K., Gurung, A., Reza, K. M., Bahrami, B., Pokharel, J., Baniya, A., He, W., Wu, F., Zhou, Y., et al. (2020) · Nature Communications · doi:10.1038/s41467-019-13774-2 · Cited by 455
Self-citationZhang, M., Li, Y., Wu, F., Bai, Y., & Wu, C. (2021) · Nano Energy · doi:10.1016/j.nanoen.2020.105738 · Cited by 412
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Metadata
- Authors
- Yuan, Y., Wu, F., Bai, Y., Li, Y., Chen, G., Wang, Z., & Wu, C.
- Venue
- Energy Storage Materials
- Publisher
- Elsevier BV
- Published
- 2019-01
- Volume
- 16
- Pages
- 411-418
- ISSN
- 2405-8289 (ISSN-L)
- 2405-8297
- OpenAlex
- W2808835797
- Cited by
- 327
- References
- 2
- FWCI
- 12.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yuan, Y., Wu, F., Bai, Y., Li, Y., Chen, G., Wang, Z., & Wu, C. (2019). Regulating Li deposition by constructing LiF-rich host for dendrite-free lithium metal anode. Energy Storage Materials. https://doi.org/10.1016/j.ensm.2018.06.022
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