Cited by 17Bauxite Residue and UtilizationGeotechnical Engineering and Soil StabilizationConcrete and Cement Materials Research

The DOI matches its Crossref record; the references it cites are not checked yet.

Phosphogypsum and carbide slag synergy for red mud soil stabilization: Mechanical performance, environmental impacts, and micro-scale mechanisms

Xi, Lei, Deng, Taisen, Ma, Qiang, Zhang, Derun, Zhang, Zeyu, Zhang, Zhenglin·2025·Environmental Research

Abstract

The production of phosphogypsum (PG), calcium carbide slag (CS), and red mud (RM) in global industrial development imposes serious environmental issues. Utilizing CS and PG as curing agents and incorporating RM as a soil substitute can facilitate the solid waste resource utilization. However, few studies have investigated the synergistic effects of PG and CS on the stabilization of RM and soil. To fulfill this research gap, this study explored the recycling of PG and CS for RM soil stabilization at varying RM ratio from 1:4 to 4:1. A series of tests on the stabilized RM soil composite were conducted, including the compaction test, unconfined compressive strength (UCS) test, consolidated-undrained triaxial compression test (CU), microscopic analyses (XRD and SEM), and toxicity characteristic leaching procedure (TCLP) test. The test results indicated that the maximum dry density (MDD) of the RM soil composite increased as the RM ratio increased from 1:4 to 4:1. When the PG content exceeds 8 %, the RM soil composite becomes loose, leading to a decrease in UC and ultimate deviatoricic stress. The synergistic effect of PG-CS can reduce the leaching of Cr, Cd, and Pb significantly by 54.6 %, 32.7 %, and 21.9 % respectively. When appropriate amounts of PG and CS are incorporated, considerable cementitious hydration products such as C-S-H/C-A-S-H and Aft will be generated. These hydration products can adhere to the surface of RM and soil particles or fill the gaps between particles, making the soil structure dense and stable, thereby significantly improving its mechanical performance. The optimal dosages of PG and CS were identified as 8 % and 12 %, respectively. The combined use of PG and CS is found to significantly enhance the strength of the RM-soil composite and inhibit the leaching of heavy metals, which promotes the large-scale utilization of solid waste of PG and CS.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1016/j.envres.2025.122696

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

The citation lists haven’t been fetched yet

References 48 · Cited by 17

Research works printed but not linked: 48

  1. An, 2022, Strength development and microstructure of sustainable geopolymers made from alkali-activated ground granulated blast-furnace slag, calcium carbide residue, and red mud, Constr. Build. Mater., 356, 10.1016/j.conbuildmat.2022.129279 · DOI
  2. Aswathy, 2019, Utility of lime and red mud in clay soil stabilization, Soil Stabil. Soil Improve, 16
  3. Baldermann, 2021, Uptake of aqueous heavy metal ions (Co2+, Cu2+ and Zn2+) by calcium-aluminium-silicate-hydrate gels, Cement Concr. Res., 147, 10.1016/j.cemconres.2021.106521 · DOI
  4. Bian, 2017, Effect of super-absorbent polymer on the undrained shear behavior of cemented dredged clay with high water content, J. Mater. Civ. Eng., 29, 10.1061/(ASCE)MT.1943-5533.0001849 · DOI
  5. Bošković, 2019, Characterization of red mud/melakaolin-based geopolymers as modified by Ca(OH)2, Mater. Tehnol., 53, 341, 10.17222/mit.2018.130 · DOI
  6. Cetin, 2013, Soil structure changes during drained and undrained triaxial shear of a clayey soil, Soils Found., 53, 628, 10.1016/j.sandf.2013.08.002 · DOI
  7. Chen, 2019, Mechanical properties and micro-mechanism of loess roadbed filling using by-product red mud as a partial alternative, Constr. Build. Mater., 16, 188, 10.1016/j.conbuildmat.2019.04.254 · DOI
  8. Chen, 2022, Waste control by waste: a comparative study on the application of carbide slag and quicklime in preparation of phosphogypsum-based ecological restoration materials, Chem. Eng. Process. Intensif, 178
  9. Chen, 2023, Analysis of the synergistic effect on the strength characteristics of modified red mud-based stabilized soil, Materials, 16, 6104, 10.3390/ma16186104 · DOI
  10. Chen, 2025, Geopolymers prepared from industrial solid waste: comprehensive properties and application prospects, Environ. Res., 278, 10.1016/j.envres.2025.121518 · DOI
  11. Dai, 2024, Preparation and performance assessment of calcium carbide slag alkali-activated red mud-based cementitious material, Constr. Build. Mater., 41
  12. Dhorey, 2025, Enhancing geotechnical properties of red mud stabilized black cotton soil with microbially induced calcite precipitation: a comprehensive performance and microstructural analysis, Arabian J. Sci. Eng., 50, 7986
  13. Ding, 2023, Enhanced phosphorus fixation in red mud-amended acidic soil subjected to periodic flooding-drying and straw incorporation, Environ. Res., 229, 10.1016/j.envres.2023.115960 · DOI
  14. Ding, 2024, Collaborative effects of red mud and phosphogypsum on geotechnical behavior of cement-stabilized dredged clay, Bull. Eng. Geol. Environ., 83, 10.1007/s10064-024-03699-6 · DOI
  15. Dong, 2023, Reuse of pretreated red mud and phosphogypsum as supplementary cementitious material, Sustain. Times, 15, 2856
  16. Du, 2021, Triaxial behavior of cement-stabilized organic matter-disseminated sand, Acta Geotechnica, 16, 211, 10.1007/s11440-020-00992-y · DOI
  17. Ge, 2022, Mechanical properties and microstructure of circulating fluidized bed fly ash and red mud-based geopolymer, Constr. Build. Mater., 340, 10.1016/j.conbuildmat.2022.127599 · DOI
  18. Hu, 2024, Cold-formed thin-walled steel walls filled with phosphogypsum subjected to lateral cyclic loading: testing and analysis, Adv. Struct. Eng., 27, 796, 10.1177/13694332241232047 · DOI
  19. Kandalai, 2025, Alkali activation of red mud and GGBS blends for expansive soil stabilization: strength, durability and leachate studies, Indian Geotech. J., 55, 1
  20. Kandalai, 2025, Geomechanical and microstructural behaviour of expansive soil stabilized with red mud and GGBS: an experimental investigation, Arabian J. Sci. Eng., 50, 7965, 10.1007/s13369-024-09171-7 · DOI
  21. Li, 2022, Modification of phosphogypsum using circulating fluidized bed fly ash and carbide slag for use as cement retarder, Constr. Build. Mater., 338, 10.1016/j.conbuildmat.2022.127630 · DOI
  22. Li, 2022, Effects of phosphogypsum on hydration properties and strength of calcium aluminate cement, Constr. Build. Mater., 7, 8398
  23. Liu, 2018, Strength properties of Bayer red mud stabilized by lime-fly ash using orthogonal experiments, Constr. Build. Mater., 166, 554, 10.1016/j.conbuildmat.2018.01.186 · DOI
  24. Ma, 2022, Microstructure and key properties of phosphogypsum-red mud-slag composite cementitious materials, Materials, 15, 6096, 10.3390/ma15176096 · DOI
  25. Matschei, 2007, The role of calcium carbonate in cement hydration, Cement Concr. Res., 7, 96
  26. Naeem, 2024, Contaminant transport from solid waste dumps: implications for environmental degradation with a focus on capital territory regions, Environ. Res., 247, 10.1016/j.envres.2024.118152 · DOI
  27. Reddy, 2016, Evaluation of the compaction characteristics of untreated and treated red mud, J. Geotechnical Mater.
  28. Schlögl, 2023, Use of industrial residues for heavy metals immobilization in contaminated site remediation: a brief review, Int. J. Environ. Sci. Technol., 20, 2313, 10.1007/s13762-022-04184-x · DOI
  29. Shen, 2025, Red mud-based magnetic biochar composite as a peroxydisulfate activator for tetracycline degradation, Environ. Res., 279
  30. Singh, 2018, Effect of mechanical activation of red mud on the strength of geopolymer binder, Constr. Build. Mater., 177, 91, 10.1016/j.conbuildmat.2018.05.096 · DOI
  31. Thakur, 2023, Utilization of industrial waste phosphogypsum as geomaterial: a review, J. Hazard. Toxic Radioact. Waste, 27, 10.1061/JHTRBP.HZENG-1181 · DOI
  32. Tian, 2023, Gneering properties of fine-grained red mud, Int. J. Min. Sci. Technol., 2, 5
  33. Wan, 2023, Evolution in macro-micro properties of cement-treated clay with changing ratio of red mud to phosphogypsum, Constr. Build. Mater., 392, 10.1016/j.conbuildmat.2023.131972 · DOI
  34. Wang, 2022, Engineering properties of soil-based controlled low-strength materials made from local red mud and silty soil, Constr. Build. Mater., 8, 9453
  35. Wang, 2023, Ailization of shield muck treated with calcium carbide slag-fly ash, Buildings, 13, 1707, 10.3390/buildings13071707 · DOI · Paper page
  36. Wang, 2025, Investigation of the properties and microscopic mechanism of red mud-phosphogypsum-based composite cementitious materials, J. Clean. Prod., 101
  37. Wang, 2025, Study on stability and applicability of calcium carbide slag—dealkalized red mud and solid waste composite materials in road materials, Mater, 18, 3140, 10.3390/ma18133140 · DOI
  38. Wu, 2022, Highly targeted solidification behavior of hazardous components in phosphogypsum, Chem. Eng. J. Adv., 9, 10.1016/j.ceja.2021.100227 · DOI
  39. Wu, 2025, Preparation of high-strength bricks by synergistic densification treatment of phosphogypsum and calcium carbide slag, Constr. Build. Mater., 470, 10.1016/j.conbuildmat.2025.140534 · DOI
  40. Xi, 2024, Investigation on strength properties of phosphogypsum-dredged soil stabilized by carbide slag activated ground granulated blast-furnace slag, Constr. Build. Mater., 457, 10.1016/j.conbuildmat.2024.139427 · DOI · Paper page
  41. Yan, 2024, Gypsum-enhanced red mud composites: a study on strength, durability, and leaching characteristics, Buildings, 14, 1979, 10.3390/buildings14071979 · DOI
  42. Yang, 2020, Potential effect of porosity evolution of cemented paste backfill on selective solidification of heavy metal ions, Int. J. Environ. Res. Publ. Health, 17, 814, 10.3390/ijerph17030814 · DOI
  43. Yong, 2019, Stabilization of a residual soil using calcium and magnesium hydroxide nanoparticles: a quick precipitation method, Appl. Sci., 9, 4325, 10.3390/app9204325 · DOI
  44. Zhang, 2025, Soil contaminated with a high concentration of copper or lead solidified with red mud-calcium slag-phosphogypsum. Structural stability in an acidic environment, J. Mater. Civ. Eng., 37, 10.1061/JMCEE7.MTENG-17800 · DOI
  45. Zhang, 2025, Soil contaminated with a high concentration of copper or lead solidified with red mud-carbide slag-phosphogypsum. Structural stability in an acidic environment, J. Mater. Civ. Eng., 37
  46. Zhou, 2024, Performance activation and strength evolution mechanism of carbide slag on anhydrous phosphogypsum backfill material, Constr. Build. Mater., 419, 10.1016/j.conbuildmat.2024.135503 · DOI
  47. Zhou, 2024, Development and property optimization of a sustainable phosphogypsum-based cementitious system with ground-granulated blast furnace slag and carbide slag, Constr. Build. Mater., 271
  48. Zhu, 2024, Study on synthesis of CSH gel and its immobilization of heavy metals, Crystals, 14, 864, 10.3390/cryst14100864 · DOI

Metadata

Authors
Xi, L., Deng, T., Ma, Q., Zhang, D., Zhang, Z., & Zhang, Z.
Affiliations
  • Hubei University of Technology (CN)
  • Huazhong University of Science and Technology (CN)
  • Wuhan University of Technology (CN)
Corresponding author
Ma, Qiang
Venue
Environmental Research
Publisher
Elsevier BV
Published
2025-12
Volume
286
Issue
Pt 1
Pages
122696
ISSN
0013-9351 (ISSN-L)
OpenAlex
W4414078567
Cited by
17
References
48
Citations by year
2026: 16 · 2025: 1
FWCI
4.64
Type
journal article
Language
en
Open access
closed
Locations
  • Environmental Research (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • Outstanding Young and Middle-aged Scientific Innovation Team of Colleges and Universities of Hubei Province (2020EJB004, T2022010)
  • Science Fund for Distinguished Young Scholars of Hubei Province (2023BAB093, 2022CFA043)
  • Hubei Province Natural Science Foundation (2023AFB323)
  • Hubei University of Technology (HGKFYBP23)
  • Ten Thousand Talent Plans for Young Top-notch Talents of Yunnan Province
  • National Natural Science Foundation of China (52478338)
Topics
  • Physical Sciences › Environmental Science › Waste Management and Disposal › Bauxite Residue and Utilization
  • Physical Sciences › Engineering › Civil and Structural Engineering › Geotechnical Engineering and Soil Stabilization
  • Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
Keywords
phosphogypsum, carbide slag, red mud, soil stabilization, solid waste recycling, heavy metal leaching, unconfined compressive strength, deviatoric stress, calcium silicate hydrate, AFt, maximum dry density, synergistic effect
MeSH terms
Calcium Sulfate, Industrial Waste, Phosphorus, Soil, Soil Pollutants, Compressive Strength, Recycling

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Phosphogypsum and carbide slag synergy for red mud soil stabilization: Mechanical performance, environmental impacts, and micro-scale mechanisms. https://app.cochat.ai/papers/10.1016/j.envres.2025.122696
The paper
Xi, L., Deng, T., Ma, Q., Zhang, D., Zhang, Z., & Zhang, Z. (2025). Phosphogypsum and carbide slag synergy for red mud soil stabilization: Mechanical performance, environmental impacts, and micro-scale mechanisms. Environmental Research. https://doi.org/10.1016/j.envres.2025.122696