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Extraction improvement of ionic liquid-functionalized silica by in situ anion-exchange for online solid-phase extraction of estrogens in honey
Abstract
The accurate detection of analytes in honey is affected by the complex substrates, making it crucial to employ an effective sample preparation technique. In this work, an imidazolium ionic liquid was functionalized to the silica surface by a click reaction for solid-phase extraction (SPE) column, and in situ anion-exchange process was performed with different organic anions (dodecyl sulfonate, dodecyl benzene sulfonate, and naphthalene sulfonate). These SPE columns were evaluated through extracting the estrogens. The naphthalene sulfonate-based SPE column displayed the best extraction ability among these, and it was combined with high-performance liquid chromatography-diode array detection to establish an online enrichment and analysis system. Under the optimal test conditions, an online analytical method was developed, with high enrichment factors (1872-4744), wide linear ranges (0.0033-1.50, 0.0165-1.50, and 0.0330-1.50 μg g-1), and low detection limits (0.001-0.010 μg g-1). The method successfully determined several estrogens in some honey samples, and achieved satisfactory recovery results.
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References 27 · Cited by 20
Research works printed but not linked: 27
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Metadata
- Authors
- Ding, Y., Feng, J., Sun, M., Feng, Y., Xin, X., & Sun, M.
- Affiliations
- University of Jinan (CN)
- Corresponding author
- Feng, Juanjuan
- Sun, Mingxia
- Sun, Min
- Venue
- Food Chemistry
- Publisher
- Elsevier BV
- Published
- 2024-07
- Volume
- 445
- Pages
- 138706
- ISSN
- 0308-8146 (ISSN-L)
- OpenAlex
- W4391905953
- Cited by
- 20
- References
- 27
- Citations by year
- 2026: 6 · 2025: 10 · 2024: 4
- FWCI
- 2.56
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Food Chemistry (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Natural Science Foundation of Shandong Province (ZR2023MB006, ZR2023MB154)
- National Natural Science Foundation of China (21405061, 21777054)
- Topics
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Life Sciences › Agricultural and Biological Sciences › Food Science › Pesticide Residue Analysis and Safety
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical Chemistry and Chromatography
- Keywords
- imidazolium ionic liquids, click chemistry, solid-phase extraction, estrogen, honey, online enrichment, naphthalene sulfonate, dodecylbenzenesulfonate, food contaminants
- MeSH terms
- Anions, Chromatography, High Pressure Liquid, Estrogens, Honey, Naphthalenes, Silicon Dioxide, Ionic Liquids, Solid Phase Extraction
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