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Effect of hydrogen blending on the high temperature auto-ignition of ammonia at elevated pressure

Chen, Jundie, Jiang, Xue, Qin, Xiaokang, Huang, Zuohua·2021·Fuel

Abstract

Abstract To understand the effect of hydrogen addition on the auto-ignition of ammonia at high temperatures, ignition delay times of stoichiometric ammonia/hydrogen blends were measured in a shock tube at temperatures from 1020 to 1945 K, pressures of 1.2 and 10 atm, and hydrogen fractions from 0% to 70%. The measured ignition delay times were compared with seven available kinetic models. Chemical kinetic analyses were performed using both the Glarborg Model and Otomo Model to interpret the interactions between ammonia and hydrogen during the high temperature auto-ignition. Experimental results show that ammonia ignites slower than hydrogen, and hydrogen addition can reduce the ignition delay time nonlinearly. The numerical analysis identifies that 5% hydrogen addition does not significantly affect the reaction flux of ammonia at 20% fuel consumption, however, it makes the fuel H-atom abstraction reaction NH3 + H NH2 + H2 proceed in the reversed way at the initial stage of ignition, therefore generate active H radical for further chain branching and promote the reactivity.

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Metadata

Authors
Chen, J., Jiang, X., Qin, X., & Huang, Z.
Venue
Fuel
Publisher
Elsevier BV
Published
2021-03
Volume
287
Pages
119563
ISSN
0016-2361 (ISSN-L)
OpenAlex
W3095041282
Cited by
331
References
58
FWCI
13.14
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Effect of hydrogen blending on the high temperature auto-ignition of ammonia at elevated pressure. https://app.cochat.ai/papers/10.1016/j.fuel.2020.119563
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Chen, J., Jiang, X., Qin, X., & Huang, Z. (2021). Effect of hydrogen blending on the high temperature auto-ignition of ammonia at elevated pressure. Fuel. https://doi.org/10.1016/j.fuel.2020.119563

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