Cited by 9Thermochemical Biomass Conversion ProcessesThermal and Kinetic AnalysisCoal Properties and Utilization

Self-heating and thermal runaway of biomass – Lab-scale experiments and modeling for conditions resembling power plant mills

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Schwarzer, Lars, Jensen, Peter Arendt, Wedel, Stig, Glarborg, Peter, Karlström, Oskar, Holm, Jens Kai, Dam-Johansen, Kim·2021·Fuel

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  • Oxygen deprivation during pyrolysis can exacerbate reactive functional groups, while low-temperature biochars like B600 retain surface tars that initiate thermal runaway.

    “Oxygen deprivation during pyrolysis can exacerbate reactive functional groups, while low-temperature biochars like B600 retain surface tars that initiate thermal runaway [39,110,111].”

    From Pilot-Scale Slow Pyrolysis, Post-Heat Treatment, and Self-Heating Performance of Biochar Fuels Derived from Construction, Renovation, and Demolition (CRD) Wood Waste (2026) · cites this paper as [39]

    The Experimental section (p. unavailable) reports no relevant self-heating during inert-atmosphere pyrolysis. The Introduction (p. unavailable) instead identifies heterogeneous oxidation of solid biomass as the likely ignition pathway under the conditions studied; the Model parameters section lists tars as pyrolysis products, not initiators of thermal runaway. The paper does not address B600 or changes in reactive functional groups. (LLM, conf=0.78)

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References 60 · Cited by 9

Research works printed but not linked: 20

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  5. R. G. Zalosch. Review of Coal Pulverizer Fire and Explosion Incidents. In Industrial Dust Explosions, ASTM STP 958, pages 191-201. American Society for Testing and Materials, 1987.
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  8. J. C. Jones. On the Extrapolation of Results from Oven Heating Tests for Propensity to Self-Heating. Combustion and Flame, 124(1-2):334-336, 2001.
  9. W. Guo. Self-Heating and Spontaneous Combustion of Wood Pellets during Storage. PhD thesis, University of British Columbia, 2013.
  10. L. Schwarzer, Z. Sárossy, P. A. Jensen, P. Glarborg, O. Karlström, J. K. Holm, and K. Dam-Johansen. Kinetic parameters for biomass under self- ignition conditions: Low-temperature oxidation and pyrolysis. Energy & Fuels, 33(9):8606-8619, 2019.
  11. W. J. Massman. A review of the molecular diffusivities of H2O, CO2, CH4, CO, O3, SO2, NH3, N2O, NO, and NO2 in air, O2 and N2 near STP. Atmospheric Environment, 32(6):1111-1127, 1998.
  12. C. W. Lautenberger. A Generalized Pyrolysis Model for Combustible Solids. PhD thesis, University of California, Berkeley, 2007.
  13. H. Lu, E. Ip, J. Scott, P. Foster, M. Vickers, and L. L. Baxter. Effects of particle shape and size on devolatilization of biomass particle. Fuel, 89(5):1156-1168, 2010.
  14. A. L. Loeb. Thermal conductivity: VIII, A theory of thermal conductivity of porous materials. Journal of the American Ceramic Society, 37(2):96-99, 1954.
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  16. M. Perzon. Emissions of organic compounds from the combustion of oats -a comparison with softwood pellets. Biomass and Bioenergy, 34(6):828-837, 2010.
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  18. L. Schwarzer. Biomass Particle Ignition in Mill Equipment. PhD thesis, DTU Chemical Engineering, 2019.
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Authors
Schwarzer, L., Jensen, P. A., Wedel, S., Glarborg, P., Karlström, O., Holm, J. K., & Dam-Johansen, K.
Affiliations
  • Technical University of Denmark (DK)
  • Åbo Akademi University (FI)
  • Ørsted (Denmark) (DK)
Corresponding author
  • Schwarzer, Lars
  • Jensen, Peter Arendt
Venue
Fuel
Publisher
Elsevier BV
Published
2021-06
Volume
294
Pages
120281
ISSN
0016-2361 (ISSN-L)
OpenAlex
W3133652643
Cited by
9
References
60
Citations by year
2026: 2 · 2025: 1 · 2024: 1 · 2023: 1 · 2022: 3 · 2021: 1
FWCI
0.46
Type
journal article
Language
en
Open access
Locations
  • Fuel (publishedVersion)
  • Åbo Akademi University Research Portal (submittedVersion, cc-by-nc-nd)
  • Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU) (submittedVersion, cc-by-nc-nd)
Funders
Academy of Finland (321598)
Topics
  • Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
  • Physical Sciences › Engineering › Ocean Engineering › Coal Properties and Utilization
Keywords
self-heating, thermal runaway, autoignition, reaction kinetics, heat and mass transfer, oxygen diffusion, sample size effects, pine pellets, wheat straw, sensitivity analysis, scaling

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