Calculating the partitioning of the isotopes of Mo between oxidic and sulfidic species in aqueous solution
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Mo isotope fractionation is due at least in part to fractionation among aqueous species, and a critical amount of sulfide is needed to ensure all Mo is in the tetrathiomolybdate phase and quantitatively scavenged.
“This isotopic fractionation is due, at least in part, to the fractionation of Mo isotopes amongst various aqueous species (Tossell, 2005), and accordingly a critical amount of sulfide is required to ensure that all Mo is in the tetrathiomolybdate phase and that Mo is quantitatively scavenged.”
From Trace elements at the intersection of marine biological and geochemical evolution (2016) · cites this paper as Tossell, 2005
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References 65 · Cited by 248
- Authors
- Tossell, J. A.
- Affiliations
- University of Maryland, College Park (US)
- Corresponding author
- Tossell, J.A.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2005-06
- Volume
- 69
- Issue
- 12
- Pages
- 2981-2993
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2012291299
- Cited by
- 248
- References
- 65
- Citations by year
- 2026: 13 · 2025: 9 · 2024: 21 · 2023: 17 · 2022: 14 · 2021: 25 · 2020: 10 · 2019: 9 · 2018: 11 · 2017: 19 · 2016: 12 · 2015: 7 · 2014: 9 · 2013: 10 · 2012: 10
- FWCI
- 5.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- molybdenum isotopes, isotope fractionation, molybdate, molybdenum sulfide, equilibrium constants, quantum chemical calculations, vibrational frequencies, molybdenum oxidation state
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