Isotopic fractionation and reaction kinetics between Cr(III) and Cr(VI) in aqueous media
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The isotopic composition of natural Cr species is mainly controlled by redox state changes, with large fractionations expected for equilibrium Cr(III)-Cr(VI) exchange and incomplete Cr(VI) reduction.
“the isotopic composition of natural Cr species is governed principally by shifts in redox state -with significant isotopic fractionations expected for both equilibrium exchange between Cr(III) and Cr(VI) species and incomplete reduction of Cr(VI) to Cr(III)”
From The chromium isotope composition of reducing and oxic marine sediments (2016) · cites this paper as Zink et al., 2010
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References 58 · Cited by 196
- Authors
- Zink, S., Schoenberg, R., & Staubwasser, M.
- Affiliations
- Leibniz University Hannover (DE)
- University of Bergen (NO)
- University of Cologne (DE)
- Corresponding author
- Zink, Sonja
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2010-10
- Volume
- 74
- Issue
- 20
- Pages
- 5729-5745
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1994318444
- Cited by
- 196
- References
- 58
- Citations by year
- 2026: 5 · 2025: 2 · 2024: 8 · 2023: 8 · 2022: 10 · 2021: 24 · 2020: 12 · 2019: 20 · 2018: 22 · 2017: 11 · 2016: 17 · 2015: 11 · 2014: 13 · 2013: 13 · 2012: 12
- FWCI
- 7.81
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Kölner Universitäts PublikationsServer (Universität zu Köln) (acceptedVersion)
- Funders
- Deutsche Forschungsgemeinschaft
- Topics
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Chromium effects and bioremediation
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- chromium isotopes, isotope fractionation, reaction kinetics, isotope exchange, chromate reduction, chromium(III) oxidation, hydrogen peroxide, chromium(V) intermediate, disproportionation, pH effect
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