Oxygen isotope fractionation between water and the aqueous hydroxide ion
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The equilibrium isotopic composition of OH- relative to H2O is -21.3 ± 2.2‰ based on quantum-chemical calculations.
“A value of -21.3 ± 2.2‰ relative to H2O for the equilibrium isotopic composition of OH -was used based on quantum-chemical calculations (Zeebe, 2020).”
From Isotopic fractionation accompanying CO2 hydroxylation and carbonate precipitation from high pH waters at The Cedars, California, USA (2021) · cites this paper as Zeebe, 2020
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References 64 · Cited by 21
- Authors
- Zeebe, R. E.
- Affiliations
- University of Hawaiʻi at Mānoa (US)
- Corresponding author
- Zeebe, Richard E.
- ORCID
- Zeebe, Richard E.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2020-11
- Volume
- 289
- Pages
- 182-195
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W3082932865
- Cited by
- 21
- References
- 64
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 5 · 2023: 1 · 2022: 7 · 2021: 5
- FWCI
- 2.23
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Advanced Chemical Physics Studies
- Keywords
- oxygen isotope fractionation, hydroxide ion, water clusters, hydrogen bonding, quantum chemical calculations, vibrational modes, anharmonicity, isotope fractionation factors, aqueous geochemistry
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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