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Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia-borane: High activity and long lifetime
Open accessAbstract
Abstract The simplest amine-borane, considered as solid hydrogen storage material, ammonia-borane (H3NBH3) can release hydrogen gas upon catalytic hydrolysis under mild conditions. Herein, we report the preparation of a novel catalyst, water dispersible laurate-stabilized ruthenium(0) nanoclusters from the dimethylamine-borane reduction of ruthenium(III) chloride in sodium laurate solution at room temperature. The ruthenium nanoclusters in average size of 2.6 ± 1.2 nm were isolated from the solution and well characterized by using TEM, XPS, FTIR, and UV–visible electronic absorption spectroscopy. The water dispersible laurate-stabilized ruthenium(0) nanoclusters were found to be highly active and long-live catalyst with a TOF of 75 mol H2/mol Ru·min and TTO value of 5900 mol H2/mol Ru in the hydrolysis of ammonia-borane at 25.0 ± 0.1 °C.
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Citations
Cites
Ni1-xPtx (x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
Cheng, F., Ma, H., Li, Y., & Chen, J. (2007) · Inorganic Chemistry · doi:10.1021/ic061712e · Cited by 349
Cited by
Ammonia-Borane and Related Compounds as Dihydrogen Sources
Staubitz, A., Robertson, A. P. M., & Manners, I. (2010) · Chemical Reviews · doi:10.1021/cr100088b · Cited by 1,247
Metadata
- Authors
- Durap, F., Zahmakıran, M., & Özkar, S.
- Venue
- International Journal of Hydrogen Energy
- Publisher
- Elsevier BV
- Published
- 2009-09
- Volume
- 34
- Issue
- 17
- Pages
- 7223-7230
- ISSN
- 0360-3199 (ISSN-L)
- OpenAlex
- W2036248390
- Cited by
- 190
- References
- 1
- FWCI
- 9.41
- Type
- journal article
- Language
- en
- Open access
- green
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- Durap, F., Zahmakıran, M., & Özkar, S. (2009). Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia-borane: High activity and long lifetime. International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2009.06.074
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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