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Rapid and energy-efficient preparation of boron doped g-C3N4 with excellent performance in photocatalytic H2-evolution
Abstract
Abstract Microwaving heating method, which shows significantly higher efficiency in synthesis time and energy utilization than conventional heating method, was firstly applied to synthesize boron doped g-C3N4 (B-g-C3N4). Results demonstrated that B-g-C3N4 could be prepared in 35 min via the method. XRD and XPS analyses verified the successfully doping of B element into the structure of g-C3N4. The doped B improved the photoabsorption performance of g-C3N4. Meanwhile, it greatly hindered the annihilation of charge carriers, prolonging the lifetime of photogenerated electrons, and thereby resulting in the excellent photocatalytic activity. The optimal B-g-C3N4 exhibited a H2 production rate of 1439 and 400 μmol g−1 h−1 under simulated sunlight and visible light irradiation, respectively. This values are about 2.4 times higher than that of pure g-C3N4. This study offered an energy-efficient and rapid way for the synthesis of external atom doped g-C3N4 with high catalytic efficiency.
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Citations
Cites
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Ge, L., Han, C., Xiao, X., & Guo, L. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.04.006 · Cited by 401
Cited by
Yang, C., Tan, Q., Li, Q., Zhou, J., Fan, J., Li, B., Sun, J., & Lv, K. (2020) · Applied Catalysis B: Environment and Energy · doi:10.1016/j.apcatb.2020.118738 · Cited by 616
Recent advances in anion doped g-C3N4 photocatalysts: A review
Patnaik, S., Sahoo, D. P., & Parida, K. (2021) · Carbon · doi:10.1016/j.carbon.2020.10.073 · Cited by 586
Recent developments of doped g-C3N4 photocatalysts for the degradation of organic pollutants
Liu, X., Ma, R., Zhuang, L., Hu, B., Chen, J., Liu, X., & Wang, X. (2021) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2020.1734433 · Cited by 565
Fu, J., Liu, K., Jiang, K., Li, H., An, P., Li, W., Zhang, N., Li, H., Xu, X., Zhou, H., et al. (2019) · Advanced Science · doi:10.1002/advs.201900796 · Cited by 355
Roles of N-Vacancies over Porous g-C3N4 Microtubes during Photocatalytic NOx Removal
Wang, Z., Huang, Y., Chen, M., Shi, X., Zhang, Y., Cao, J., Ho, W., & Lee, S. C. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b21987 · Cited by 287
Metadata
- Authors
- Chen, P., Xing, P., Chen, Z., Lin, H., & He, Y.
- Venue
- International Journal of Hydrogen Energy
- Publisher
- Elsevier BV
- Published
- 2018-10
- Volume
- 43
- Issue
- 43
- Pages
- 19984-19989
- ISSN
- 0360-3199 (ISSN-L)
- OpenAlex
- W2894819055
- Cited by
- 178
- References
- 2
- FWCI
- 4.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, P., Xing, P., Chen, Z., Lin, H., & He, Y. (2018). Rapid and energy-efficient preparation of boron doped g-C3N4 with excellent performance in photocatalytic H2-evolution. International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2018.09.078
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