Cited by 1,356Hybrid Renewable Energy SystemsHydrogen Storage and MaterialsChemical Looping and Thermochemical Processes

Large-scale storage of hydrogen

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Andersson, Joakim, Grönkvist, Stefan·2019·International Journal of Hydrogen Energy

Abstract

The large-scale storage of hydrogen plays a fundamental role in a potential future hydrogen economy. Although the storage of gaseous hydrogen in salt caverns already is used on a full industrial scale, the approach is not applicable in all regions due to varying geological conditions. Therefore, other storage methods are necessary. In this article, options for the large-scale storage of hydrogen are reviewed and compared based on fundamental thermodynamic and engineering aspects. The application of certain storage technologies, such as liquid hydrogen, methanol, ammonia, and dibenzyltoluene, is found to be advantageous in terms of storage density, cost of storage, and safety. The variable costs for these high-density storage technologies are largely associated with a high electricity demand for the storage process or with a high heat demand for the hydrogen release process. If hydrogen is produced via electrolysis and stored during times of low electricity prices in an industrial setting, these variable costs may be tolerable.

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Crossref · 10.1016/j.ijhydene.2019.03.063

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  • The evaporation of hydrogen during storage results in two different losses: the energy loss for liquefaction and the hydrogen loss due to purging of the evaporated gas to avoid pressure buildup inside the vessel.

    “The evaporation of hydrogen during storage results in two different losses: the energy loss for liquefaction and the hydrogen loss due to purging of the evaporated gas to avoid pressure buildup inside the vessel [37].”

    From 5917. https://doi.org/10.3390/en14185917. - (2021) · cites this paper as [37]

  • Boil-off can be minimized (zero boil-off) through various active and passive efforts, such as acceleration of isomer change from ortho- to para-hydrogen during liquefaction, minimization of surface-to-volume ratio of the vessel, excellent insulation of the vessel, and the adoption of a cryocooler.

    “The boil-off can be minimized (zero boil-off) through various active and passive efforts, such as acceleration of isomer change from ortho-to para-hydrogen during liquefaction, minimization of surface-to-volume ratio of the vessel (such as spherical shape), excellent insulation of the vessel to reduce the heat transfer from the surrounding environment, and the adoption of a cryocooler [37].”

    From 5917. https://doi.org/10.3390/en14185917. - (2021) · cites this paper as [37]

  • In practical applications, the specific energy demand for hydrogen liquefaction is approximately 10 kWh_el/kg-H2, although it is predicted that the demand can be reduced to approximately 6 kWh_el/kg-H2 with further process improvements.

    “However, in practical applications, the specific energy demand for hydrogen liquefaction is approximately 10 kWh el /kg-H 2 , although it is predicted that the demand can be reduced to approximately 6 kWh el /kg-H 2 with further process improvements [37,94].”

    From 5917. https://doi.org/10.3390/en14185917. - (2021) · cites this paper as [37]

  • Through excellent insulation and a low surface-to-volume ratio (large spherical tank), the boil-off can be suppressed to less than 0.1% per day.

    “Through excellent insulation and a low surface-to-volume ratio (large spherical tank), the boil-off can be suppressed to less than 0.1% per day [37].”

    From 5917. https://doi.org/10.3390/en14185917. - (2021) · cites this paper as [37]

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References 167 · Cited by 1,356

Authors
Andersson, J., & Grönkvist, S.
Affiliations
KTH Royal Institute of Technology (SE)
Corresponding author
Andersson, Joakim
Venue
International Journal of Hydrogen Energy
Publisher
Elsevier BV
Published
2019-05
Volume
44
Issue
23
Pages
11901-11919
ISSN
0360-3199 (ISSN-L)
OpenAlex
W2929651773
Cited by
1,356
References
167
Citations by year
2026: 175 · 2025: 229 · 2024: 259 · 2023: 226 · 2022: 207 · 2021: 132 · 2020: 105 · 2019: 23
FWCI
40.91
Type
journal article
Language
en
Update notices
erratum (2022-01-05)
Open access
Locations
International Journal of Hydrogen Energy (publishedVersion, cc-by)
Funders
Swedish Energy Agency
Topics
  • Physical Sciences › Energy › Energy Engineering and Power Technology › Hybrid Renewable Energy Systems
  • Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
  • Physical Sciences › Engineering › Biomedical Engineering › Chemical Looping and Thermochemical Processes
Keywords
hydrogen storage, hydrogen economy, salt cavern storage, liquid hydrogen, ammonia hydrogen carrier, dibenzyltoluene, storage density, storage costs, storage safety, electrolysis, thermodynamic analysis

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