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Comparative study of anion exchange membranes for low-cost water electrolysis
Abstract
Abstract Various anion-exchange membranes (AEMs) were studied in the electrolysis cell using the non-precious metal-based catalysts showing the good potential of selected AEMs in low-cost water electrolysis application. The 0.1–1 M potassium hydroxide electrolyte is applied for high performance electrolysis process, whereas the usage of pure water leads to the significant AEM resistance increase. The post mortem MEA analysis, using SEM is performed to study the structure and morphology of catalyst layers transferred from the electrodes prepared by catalyst coated substrate approach. The importance of the catalyst layer–membrane interface and the binder used to bond the catalyst layer is discussed. AEM electrolysis safety aspect in terms of the hydrogen crossover through the 28 μm thin A-201 membrane is studied. The linear dependency of the permeated hydrogen flux on current density is shown. Hydrogen content in the anode outlet gas is less enough to ensure high safety of the AEM electrolysis technology in the operating currents range.
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Cites
Morphological features (defects) in fuel cell membrane electrode assemblies
Kundu, S., Fowler, M. W., Simon, L. C., & Grot, S. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.12.027 · Cited by 244
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An overview of water electrolysis technologies for green hydrogen production
Shiva Kumar, S., & Lim, H. (2022) · Energy Reports · doi:10.1016/j.egyr.2022.10.127 · Cited by 1,526
Overview: State-of-the Art Commercial Membranes for Anion Exchange Membrane Water Electrolysis
Henkensmeier, D., Najibah, M., Harms, C., Žitka, J., Hnát, J., & Bouzek, K. (2021) · Journal of Electrochemical Energy Conversion and Storage · doi:10.1115/1.4047963 · Cited by 382
Wan, L., Xu, Z., Xu, Q., Pang, M., Lin, D., Liu, J., & Wang, B. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00142c · Cited by 371
Jiang, W., Faid, A. Y., Gomes, B. F., Galkina, I., Xia, L., Lobo, C. M. S., Desmau, M., Borowski, P., Hartmann, H., Maljusch, A., et al. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202203520 · Cited by 161
Anion Exchange Membrane Water Electrolysis Based on Nickel Ferrite Catalysts
Caprì, A., Gatto, I., Lo Vecchio, C., Trocino, S., Carbone, A., & Baglio, V. (2023) · ChemElectroChem · doi:10.1002/celc.202201056 · Cited by 57
Metadata
- Authors
- Pushkareva, I. V., Pushkarev, A. S., Grigoriev, S. A., Modisha, P., & Bessarabov, D. G.
- Venue
- International Journal of Hydrogen Energy
- Publisher
- Elsevier BV
- Published
- 2020-10
- Volume
- 45
- Issue
- 49
- Pages
- 26070-26079
- ISSN
- 0360-3199 (ISSN-L)
- OpenAlex
- W2990139082
- Cited by
- 198
- References
- 1
- FWCI
- 4.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pushkareva, I. V., Pushkarev, A. S., Grigoriev, S. A., Modisha, P., & Bessarabov, D. G. (2020). Comparative study of anion exchange membranes for low-cost water electrolysis. International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2019.11.011
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