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Construction of hierarchical cobalt-molybdenum selenide hollow nanospheres architectures for high performance battery-supercapacitor hybrid devices
Abstract
Transition metal selenides have aroused widespread attention as a class of emerging electrode materials for high-performance supercapacitors attributed to their featured with high theoretical capacitance and low electronegativity. Nevertheless, their practical applications are seriously restricted by the large volume expansion during high-rate charge/discharge. It is imperative to reasonably construct tunable composition and attractive architectures for electrode materials at nanoscale to mitigate the issues. Herein, hierarchical cobalt-molybdenum selenide (denoted as CoSe 2 /MoSe 2 -3-1) hollow nanospheres architectures are purposefully prepared via an efficient gas bubble-templated method combined with post-annealing process. Benefiting from the rationally hierarchical hollow structures and maximized utilization ratio of active materials, the novel bimetallic selenides acquire superior electrochemical performance with high specific capacity (211.97 mA h g -1 at 1 A g -1 ) and remarkable cycling stability (94.2% capacity retention over 2000 cycles at 3 A g -1 ). Significantly, the assembled CoSe 2 /MoSe 2 -3-1//activated carbon (AC) battery-supercapacitor hybrid (BSH) device renders a high energy density up to 51.84 W h kg -1 at a power density of 799.2 W kg -1 and preeminent cycling stability with 93.4% retention over 10,000 cycles. The present work provides an effective and rational design route to engineer advanced bimetallic selenides with hierarchical hollow structures…
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“In particular, the electrochemical properties of mixed-valent bimetallic selenides (MMSe) can be dramatically optimized by combining hetero-metallic ions for synergistic effects [27].”
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Metadata
- Authors
- Ma, F., Lu, J., Pu, L., Wang, W., & Dai, Y.
- Affiliations
- Southwest University of Science and Technology (CN)
- Corresponding author
- Dai, Yatang
- Venue
- Journal of Colloid and Interface Science
- Publisher
- Elsevier BV
- Published
- 2020-03
- Volume
- 563
- Pages
- 435-446
- ISSN
- 0021-9797 (ISSN-L)
- OpenAlex
- W2998372063
- Cited by
- 121
- References
- 62
- Citations by year
- 2026: 11 · 2025: 12 · 2024: 22 · 2023: 23 · 2022: 19 · 2021: 18 · 2020: 16
- FWCI
- 4.11
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Colloid and Interface Science (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Southwest University of Science and Technology
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
- Keywords
- bimetallic selenides, hollow nanospheres, hierarchical nanostructures, hybrid supercapacitors, post-annealing, supercapacitor electrodes, lithium-ion battery electrodes, cycling stability, energy density, transition metal selenides
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- Ma, F., Lu, J., Pu, L., Wang, W., & Dai, Y. (2020). Construction of hierarchical cobalt-molybdenum selenide hollow nanospheres architectures for high performance battery-supercapacitor hybrid devices. Journal of Colloid and Interface Science. https://doi.org/10.1016/j.jcis.2019.12.101