The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.
Designing oxygen vacancy mediated bismuth molybdate (Bi2MoO6)/N-rich carbon nitride (C3N5) S-scheme heterojunctions for boosted photocatalytic removal of tetracycline antibiotic and Cr(VI): Intermediate toxicity and mechanism insight
Abstract
Polymeric N-rich carbon nitride of C3N5 is being utilized as a new visible-light-driven catalyst due to its narrower bandgap (∼2.0 eV). Building step-scheme (S-scheme) heterojunction by coupling with other semiconductors especially those own oxygen vacancies (OVs) can further upgrade the photocatalytic performance of C3N5-based photocatalysts. Herein, a novel S-scheme heterojunction of OVs mediated Bi2MoO6/C3N5 was fabricated by in-situ growing Bi2MoO6 nanoparticles with OVs on C3N5 nanosheets. Benefiting from the efficient separation and transfer of high energetic charge carriers by S-scheme charge migration, enriched structural defects, as well as the close contact by the in-situ growth, the heterojunction exhibited superior visible-light photocatalytic performance toward the removal of tetracycline (TC) and Cr(VI) than C3N5, Bi2MoO6, and their mechanical mixture under visible light. The TC degradation routes and the bio-toxicity evolution of TC were explored. Moreover, the photocatalytic mechanism for TC decomposition and Cr(VI) reduction over Bi2MoO6/C3N5 with OVs were elucidated. This work presents a newfangled vision for designing promising C3N5-based S-scheme heterojunction photocatalysts for pollution control.
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Cites
g‐C3N4‐Based Heterostructured Photocatalysts
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Emerging S‐Scheme Photocatalyst
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Metadata
- Authors
- Li, S., Wang, C., Cai, M., Liu, Y., Dong, K., & Zhang, J.
- Venue
- Journal of Colloid and Interface Science
- Publisher
- Elsevier BV
- Published
- 2022-10
- Volume
- 624
- Pages
- 219-232
- ISSN
- 0021-9797 (ISSN-L)
- OpenAlex
- W4281622586
- Cited by
- 284
- References
- 51
- FWCI
- 11.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, S., Wang, C., Cai, M., Liu, Y., Dong, K., & Zhang, J. (2022). Designing oxygen vacancy mediated bismuth molybdate (Bi2MoO6)/N-rich carbon nitride (C3N5) S-scheme heterojunctions for boosted photocatalytic removal of tetracycline antibiotic and Cr(VI): Intermediate toxicity and mechanism insight. Journal of Colloid and Interface Science. https://doi.org/10.1016/j.jcis.2022.05.151
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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