Methanol synthesis through CO2 capture and hydrogenation: Thermal integration, energy performance and techno-economic assessment

Summary for Policymakers

(2014) · Climate Change 2013 – The Physical Science Basis · doi:10.1017/cbo9781107415324.004 · Cited by 23,880

Analysis, synthesis, and design of chemical processes

(1998) · Choice Reviews Online · doi:10.5860/choice.36-0974 · Cited by 3,434

Renewable Power-to-Gas: A technological and economic review

Götz, M., Lefebvre, J., Mörs, F., Koch, A. M., Graf, F., Bajohr, S., Reimert, R., & Kolb, T. (2015) · Renewable Energy · doi:10.1016/j.renene.2015.07.066 · Cited by 2,587

Carbon capture and storage update

Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386

A Process for Capturing CO2 from the Atmosphere

Keith, D. W., Holmes, G., St. Angelo, D., & Heidel, K. (2018) · Joule · doi:10.1016/j.joule.2018.05.006 · Cited by 1,910

Hydrogen Production From Water Electrolysis: Current Status and Future Trends

Ursúa, A., Gandía, L. M., & Sanchis, P. (2011) · Proceedings of the IEEE · doi:10.1109/jproc.2011.2156750 · Cited by 1,716

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels

Centi, G., & Perathoner, S. (2009) · Catalysis Today · doi:10.1016/j.cattod.2009.07.075 · Cited by 1,477

Principles of Gas Absorption.

Lewis, W. K., & Whitman, W. G. (1924) · Industrial & Engineering Chemistry · doi:10.1021/ie50180a002 · Cited by 1,457

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol

Studt, F., Sharafutdinov, I., Abild‐Pedersen, F., Elkjær, C. F., Hummelshøj, J. S., Dahl, S., Chorkendorff, I., & Nørskov, J. K. (2014) · Nature Chemistry · doi:10.1038/nchem.1873 · Cited by 1,088

Methanol synthesis using captured CO2 as raw material: Techno-economic and environmental assessment

Pérez–Fortes, M., Schöneberger, J. C., Boulamanti, A. K., & Tzimas, E. (2015) · Applied Energy · doi:10.1016/j.apenergy.2015.07.067 · Cited by 871

Powering the Future with Liquid Sunshine

Shih, C. F., Zhang, T., Li, J., & Bai, C. (2018) · Joule · doi:10.1016/j.joule.2018.08.016 · Cited by 864

Design and simulation of a methanol production plant from CO2 hydrogenation

Van-Dal, É. S., & Bouallou, C. (2013) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2013.06.008 · Cited by 634

Technical Summary: Global warming of 1.5°C. An IPCC Special Report on the impacts of global warming of 1.5°C above pre-industrial levels and related global greenhouse gas emission pathways, in the context of strengthening the global response to the threat of climate change, sustainable development, and efforts to eradicate poverty

Allen, M. A., Antwi‐Agyei, P., Aragón‐Durand, F., Babiker, M. H., Bertoldi, P., Bind, M., Brown, S. A., Buckeridge, M. S., Camilloni, I. A., Cartwright, A., et al. (2019) · Cited by 521

Methanol Synthesis from CO2 Hydrogenation

Bowker, M. (2019) · ChemCatChem · doi:10.1002/cctc.201900401 · Cited by 362

Experience with CO2 capture from coal flue gas in pilot-scale: Testing of different amine solvents

Knudsen, J. N., Jensen, J. N., Vilhelmsen, P. J., & Biede, O. (2009) · Energy Procedia · doi:10.1016/j.egypro.2009.01.104 · Cited by 336

Carbon Dioxide Hydrogenation To Form Methanol via a Reverse-Water-Gas-Shift Reaction (the CAMERE Process)

Joo, O., Jung, K., Moon, I., Rozovskii, A. Y., Lin, G. I., Han, S.-H., & Uhm, S. (1999) · Industrial & Engineering Chemistry Research · doi:10.1021/ie9806848 · Cited by 323

State-of-the art CAPEX data for water electrolysers, and their impact on renewable hydrogen price settings

Proost, J. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.07.164 · Cited by 300

Post combustion CO2 capture by reactive absorption: Pilot plant description and results of systematic studies with MEA

Notz, R., Mangalapally, H. P., & Hasse, H. (2011) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2011.11.004 · Cited by 294

Feasibility study of methanol production plant from hydrogen and captured carbon dioxide

Bellotti, D., Rivarolo, M., Magistri, L., & Massardo, A. F. (2017) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2017.07.001 · Cited by 242

Investigation of technical and economic aspects for methanol production through CO 2 hydrogenation

Atsonios, K., Panopoulos, K. D., & Kakaras, E. C. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2015.12.074 · Cited by 238

High-pressure advantages in stoichiometric hydrogenation of carbon dioxide to methanol

Gaikwad, R., Bansode, A., & Urakawa, A. (2016) · Journal of Catalysis · doi:10.1016/j.jcat.2016.02.005 · Cited by 183

Power-to-fuels via solid-oxide electrolyzer: Operating window and techno-economics

Wang, L., Chen, M., Küngas, R., Lin, T., Diethelm, S., Marechal, F. M. A., & herle, J. V. (2019) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2019.04.071 · Cited by 170

A model-based analysis of CO2 utilization in methanol synthesis plant

Milani, D., Khalilpour, K. R., Zahedi, G., & Abbas, A. (2015) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2015.02.003 · Cited by 153

Clean coal technologies in China based on methanol platform

Xu, X., Liu, Y., Zhang, F., Di, W., & Zhang, Y. (2017) · Catalysis Today · doi:10.1016/j.cattod.2017.05.070 · Cited by 148

Thermodynamic Modeling and Assessment of Ionic Liquid-Based CO2 Capture Processes

Huang, Y., Zhang, X., Zhang, S., Dong, H., & Zhang, S. (2014) · Industrial & Engineering Chemistry Research · doi:10.1021/ie501538e · Cited by 141

Catalytic activation of CO2: Use of secondary CO2 for the production of synthesis gas and for methanol synthesis over copper-based zirconia-containing catalysts

Raudaskoski, R., Turpeinen, E., Lenkkeri, R., Pongrácz, É., & Keiski, R. L. (2009) · Catalysis Today · doi:10.1016/j.cattod.2008.11.026 · Cited by 140

Techno-economic barriers of an industrial-scale methanol CCU-plant

Nyári, J., Magdeldin, M., Larmi, M., Järvinen, M., & Santasalo-Aarnio, A. (2020) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2020.101166 · Cited by 133

Waste-to-methanol: Process and economics assessment

Iaquaniello, G., Centi, G., Salladini, A., Palo, E., Perathoner, S., & Spadaccini, L. (2017) · Bioresource Technology · doi:10.1016/j.biortech.2017.06.172 · Cited by 132

Green Synthetic Fuels: Renewable Routes for the Conversion of Non-Fossil Feedstocks into Gaseous Fuels and Their End Uses

Rozzi, E., Minuto, F. D., Lanzini, A., & Leone, P. (2020) · Energies · doi:10.3390/en13020420 · Cited by 121

Chemical Equilibria in Methanol Synthesis Including the Water–Gas Shift Reaction: A Critical Reassessment

Graaf, G. H., & Winkelman, J. G. M. (2016) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6b00815 · Cited by 106

A promising low pressure methanol synthesis route from CO 2 hydrogenation over Pd@Zn core–shell catalysts

Liao, F., Wu, X., Zheng, J., Li, M. M., Kroner, A., Zeng, Z., Hong, X., Yuan, Y., Gong, X., & Tsang, S. C. E. (2016) · Green Chemistry · doi:10.1039/c6gc02366e · Cited by 106

Study of CO2 removal in natural gas process using mixture of ionic liquid and MEA through process simulation

Akinola, T. E., Oko, E., & Wang, M. (2018) · Fuel · doi:10.1016/j.fuel.2018.08.152 · Cited by 89

Economic feasibility of methanol synthesis as a method for CO2 reduction and energy storage

Bellotti, D., Rivarolo, M., & Magistri, L. (2019) · Energy Procedia · doi:10.1016/j.egypro.2019.01.730 · Cited by 63

Thermodynamic analysis of combined cycle gas turbine power plant with post-combustion CO 2 capture and exhaust gas recirculation

Canepa, R., Wang, M., Biliyok, C., & Satta, A. (2012) · Proceedings of the Institution of Mechanical Engineers Part E Journal of Process Mechanical Engineering · doi:10.1177/0954408912469165 · Cited by 60

Power-to-X and power-to-power routes

Buffo, G., Marocco, P., Ferrero, D., Lanzini, A., & Santarelli, M. (2019) · Elsevier eBooks · doi:10.1016/b978-0-12-814853-2.00015-1 · Cited by 57

A Microfluidic Cell Stretch Device to Investigate the Effects of Stretching Stress on Artery Smooth Muscle Cell Proliferation in Pulmonary Arterial Hypertension

Sato, K., Nitta, M., & Ogawa, A. (2018) · Inventions · doi:10.3390/inventions4010001 · Cited by 43

Unraveling the CO2 reaction mechanism in bio-based amino-acid ionic liquids by operando ATR-IR spectroscopy

Latini, G., Signorile, M., Crocellà, V., Bocchini, S., Pirri, C. F., & Bordiga, S. (2019) · Catalysis Today · doi:10.1016/j.cattod.2018.12.050 · Cited by 41

The impact of the development of catalyst and reaction system of the methanol synthesis stage on the overall profitability of the entire plant: A techno-economic study

Alsuhaibani, A. S., Afzal, S., Challiwala, M. S., Elbashir, N. O., & El‐Halwagi, M. M. (2019) · Catalysis Today · doi:10.1016/j.cattod.2019.03.070 · Cited by 40

Simulation of CO2 Capture by MEA Scrubbing with a Rate-Based Model

Moioli, S., Pellegrini, L. A., & Gamba, S. (2012) · Procedia Engineering · doi:10.1016/j.proeng.2012.07.558 · Cited by 40

Advanced Amine Process Technology Operations and Results from Demonstration Facility at EDF Le Havre

Baburao, B., Bedell, S., Restrepo, P., Schmidt, D., Schubert, C. N., DeBolt, B., Haji, I., & Chopin, F. (2014) · Energy Procedia · doi:10.1016/j.egypro.2014.11.649 · Cited by 31

Theoretical and Experimental Studies of CoGa Catalysts for the Hydrogenation of CO2 to Methanol

Singh, J. A., Cao, A., Schumann, J., Wang, T., Nørskov, J. K., Abild‐Pedersen, F., & Bent, S. F. (2018) · Catalysis Letters · doi:10.1007/s10562-018-2542-x · Cited by 22

Mixed Logic Dynamic Models for MPC Control of Wind Farm Hydrogen-Based Storage Systems

Shehzad, M. F., Abdelghany, M. B., Liuzza, D., Mariani, V., & Glielmo, L. (2019) · Inventions · doi:10.3390/inventions4040057 · Cited by 22

Process simulation and analysis of carbon capture with an aqueous mixture of ionic liquid and monoethanolamine solvent

Zacchello, B., Oko, E., Wang, M., & Aloui, F. (2016) · International Journal of Coal Science & Technology · doi:10.1007/s40789-016-0150-1 · Cited by 20

D4.6 CEMCAP comparative techno-economic analysis of CO2 capture in cement plants

Voldsund, M., Anantharaman, R., Berstad, D., Lena, E. D., Fu, C., Gardarsdottir, S., Jamali, A., Pérez‐Calvo, J., Romano, M., Roussanaly, S., et al. (2019) · Zenodo (CERN European Organization for Nuclear Research) · doi:10.5281/zenodo.2597090 · Cited by 20

Process Equipment, Cost Scale-up

Remer, D. S., & Chai, L. H. (1993) · Scholarship - Claremont (Claremont Colleges) · Cited by 17

Renewable methanol production from green hydrogen and captured CO2: A techno-economic assessment

Sollai, S., Porcu, A., Tola, V., Ferrara, F., & Pettinau, A. (2022) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2022.102345 · Cited by 386

The effect of methanol production and application in internal combustion engines on emissions in the context of carbon neutrality: A review

Tian, Z. Q., Wang, Y., Zhen, X., & Liu, Z. (2022) · Fuel · doi:10.1016/j.fuel.2022.123902 · Cited by 329

Methanol as a renewable energy carrier: An assessment of production and transportation costs for selected global locations

Schorn, F., Breuer, J., Samsun, R. C., Schnorbus, T., Heuser, B., Peters, R., & Stolten, D. (2021) · Advances in Applied Energy · doi:10.1016/j.adapen.2021.100050 · Cited by 215

Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol

Tabibian, S. S., & Sharifzadeh, M. (2023) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2023.113281 · Cited by 235

Techno-economic assessment of long-term methanol production from natural gas and renewables

del Pozo, C. A., Cloete, S. W. P., & Álvaro, Á. J. (2022) · Energy Conversion and Management · doi:10.1016/j.enconman.2022.115785 · Cited by 120

Renewable methanol production from green hydrogen and captured CO2: A techno-economic assessment

Sollai, S., Porcu, A., Tola, V., Ferrara, F., & Pettinau, A. (2022) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2022.102345 · Cited by 386

System-level thermal integration and electrification of carbon capture and methanol synthesis

Yuan, R., Xu, K., Du, Z., Liu, D., Li, K., & Wang, H. (2026) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2026.103442

Synergistic optimization of renewable Energy-Driven methanol Synthesis: Coupling alkaline water electrolysis and CO2 hydrogenation with Full-Chain performance analysis

Wang, Z., Liu, T., He, Y., Kong, H., Cao, C., Kang, K., Tang, C., Xie, Q., Huang, H., & Wen, C. (2026) · Sustainable Energy Technologies and Assessments · doi:10.1016/j.seta.2026.104855 · Cited by 2

Techno-economic analysis and life-cycle assessment of methanol synthesis plants using renewable hydrogen and carbon dioxide feedstocks

Douglas, C. M., Lai, H., Ostadi, M., Shin, W. J., Bromberg, L., & Zang, G. (2025) · Energy Conversion and Management · doi:10.1016/j.enconman.2025.120374 · Cited by 46

Thermodynamics, economic and carbon emission analysis of power-to-methanol process through alkaline electrolysis and monoethanolamine (MEA) carbon capture

Li, Q., Khosravi, A., Farsaei, A., & Sun, L. N. (2024) · Chemical Engineering Science · doi:10.1016/j.ces.2024.120029 · Cited by 30