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Cited by 43Adsorption and biosorption for pollutant removalZeolite Catalysis and SynthesisConcrete and Cement Materials Research

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Clinoptilolite based zeolite-geopolymer hybrid foams: Potential application as low-cost sorbents for heavy metals

Liu, Yi, Zhao, Shuanghui, Qiu, Xiumei, Meng, Yi, Wang, Hongquan, Zhou, Sen, Qiao, Qiancheng, Yan, Chunjie·2023·Journal of Environmental Management
DOI 10.1016/j.jenvman.2022.117167
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Abstract

Clinoptilolite based zeolite-geopolymer foams (abbreviated as CFs) were prepared from natural clinoptilolite and calcined clinoptilolite, using H 2 O 2 solution as pore former through a straightforward process. Natural clinoptilolite and CFs are characterized by analytical techniques including optical microscope, XRF, FTIR, XRD, BET, MIP and SEM. The obtained CFs possesses micropores of zeolite and meso/macropores of geopolymer matrix. The porosities range from 66.7 to 69.5%. Clinoptilolite (partially dissolved) and impurity minerals (montmorillonite, illite and albite) contribute to the formation of geopolymer. CFs shows a good static sorption performance for toxic heavy metals at pH = 5 and sorption time of 24 h. Results show that the adsorption amount of CFs for Cr 3+, Pb 2+, Ni 2+, Cu 2+ and Cd 2+ in the 50 mg/L working solutions are 6.21 mg/g, 6.11-6.13 mg/g, 5.92-6.07 mg/g, 5.53-5.93 mg/g and 5.44-5.79 mg/g, respectively. In addition, CFs could reach a high removal rate (Cr removal rate >80% and Cd > 60%) for different heavy metals after three cycles. The elimination order of toxic metals is Cr 3+ > Pb 2+ > Ni 2+ > Cu 2+ > Cd 2+. The sequence is in accordance with Hard-Soft-Acid-Base principle, it is also related to the speciation and the ionic radii of the hydrated metal ions. This research provides a feasible approach for preparation of promising foams sorbent based on natural zeolite for wastewater management.

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Metadata

Authors
Liu, Y., Zhao, S., Qiu, X., Meng, Y., Wang, H., Zhou, S., Qiao, Q., & Yan, C.
Affiliations
China University of Geosciences (CN)
Corresponding author
Yan, Chunjie
ORCID
Venue
Journal of Environmental Management
Publisher
Elsevier BV
Published
2023-03
Volume
330
Pages
117167
ISSN
0301-4797 (ISSN-L)
DOI
10.1016/j.jenvman.2022.117167
OpenAlex
W4313340070
Cited by
43
References
0
Citations by year
2026: 10 · 2025: 15 · 2024: 15 · 2023: 3
FWCI
2.41
Type
journal article
Language
en
Open access
closed
Licence
Locations
  • Journal of Environmental Management (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
  • Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
Keywords
clinoptilolite, heavy metal adsorption, heavy metal removal, chromium, lead, nickel, copper, cadmium, natural zeolite, wastewater treatment, sorption capacity, sorption selectivity, hard-soft acid-base theory, metal speciation, ionic radius
MeSH terms
Adsorption, Cadmium, Humans, Hydrogen Peroxide, Ions, Lead, Water Pollutants, Chemical, Zeolites, Metals, Heavy

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