The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Carbonate-induced enhancement of phenols degradation in CuS/peroxymonosulfate system: A clear correlation between this enhancement and electronic effects of phenols substituents
Abstract
This study investigated the enhancement effects of dissolved carbonates on the peroxymonosulfate-based advanced oxidation process with CuS as a catalyst. It was found that the added CO 32- increased both the catalytic activity and the stability of the catalyst. Under optimized reaction conditions in the presence of CO 32-, the degradation removal of 4-methylphenol (4-MP) within 2 min reached 100%, and this was maintained in consecutive multi-cycle experiments. The degradation rate constant of 4-MP was 2.159 min-1, being 685% greater than that in the absence of CO 32- (0.315 min-1). The comparison of dominated active species and 4-MP degradation pathways in both CO 32--free and CO 32--containing systems suggested that more CO 3•-/1 O 2 was produced in the case of CO 32-deducing an electron transfer medium, which tending to react with electron-rich moieties. Meanwhile, Characterization by X-ray photoelectron spectroscopic and cyclic voltammetry measurement verified CO 32- enabled the effective reduction of Cu 2+ to Cu+. By investigating the degradation of 11 phenolics with different substituents, the dependence of degradation kinetic rate constant of the phenolics on their chemical structures indicated that there was a good linear relationship between the Hammett constants σ p of the aromatic phenolics and the logarithm of k in the CO 32--containing system. This work provides a new strategy for efficient removal of electron-rich moieties under the driving of carbonate being widely present in actual water bodies.
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“Among these derivatives, phenol with electron-donating groups, such as isopropyl, methyl, methoxy, and amino groups, undergo faster degradation compared to phenol in the presence of CO3 2 -and vice versa [72].”
From Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review (2023) · cites this paper as [72]
Citations
Cites
Activation of Peroxymonosulfate by Benzoquinone: A Novel Nonradical Oxidation Process
Zhou, Y., Jiang, J., Gao, Y., Ma, J., Pang, S., Li, J., Lu, X., & Yuan, L.-P. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b03595 · Cited by 1,279
Self-citationShao, P., Tian, J., Yang, F., Duan, X., Gao, S., Shi, W., Luo, X., Cui, F., Luo, S., & Wang, S. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201705295 · Cited by 696
Zhang, P., Yang, Y., Duan, X., Liu, Y., & Wang, S. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03099 · Cited by 453
Huang, K. Z., & Zhang, H. J. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b03648 · Cited by 409
Liu, Z., Ding, H., Zhao, C. J., Wang, T., Wang, P., & Dionysiou, D. D. (2019) · Water Research · doi:10.1016/j.watres.2019.04.052 · Cited by 349
Li, Y., Dong, H., Li, L., Tang, L., Tian, R., Li, R., Chen, J., Xie, Q., Jin, Z., Xiao, J., et al. (2021) · Water Research · doi:10.1016/j.watres.2021.116850 · Cited by 349
Gao, J., Duan, X., Ο'Shea, K. Ε., & Dionysiou, D. D. (2019) · Water Research · doi:10.1016/j.watres.2019.115394 · Cited by 325
Yan, J., Li, J., Peng, J., Zhang, H., Zhang, Y., & Lai, B. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.11.074 · Cited by 308
Photochemical degradation of oxytetracycline: Influence of pH and role of carbonate radical
Liu, Y., He, X., Duan, X., Fu, Y., & Dionysiou, D. D. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.04.048 · Cited by 270
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Rayaroth, M. P., Boczkaj, G., Aubry, O., Aravind, U. K., & Aravindakumar, C. T. (2023) · Water · doi:10.3390/w15081615 · Cited by 171
“Among these derivatives, phenol with electron-donating groups, such as isopropyl, methyl, methoxy, and amino groups, undergo faster degradation compared to phenol in the presence of CO − and vice versa [72].”
Metadata
- Authors
- Wang, X., Zhou, Y., Wang, N., Zhang, J., & Zhu, L.
- Affiliations
- Hubei Polytechnic University (CN)
- Huazhong University of Science and Technology (CN)
- Corresponding author
- Zhu, Lihua
- Venue
- Journal of Environmental Sciences
- Publisher
- Elsevier BV
- Published
- 2023-07
- Volume
- 129
- Pages
- 139-151
- ISSN
- 1001-0742 (ISSN-L)
- OpenAlex
- W4297200841
- Cited by
- 30
- References
- 38
- Citations by year
- 2026: 6 · 2025: 12 · 2024: 7 · 2023: 5
- FWCI
- 1.75
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Environmental Sciences (publishedVersion)
- PubMed (publishedVersion)
- Funders
- China Postdoctoral Science Foundation (2018M642850)
- Natural Science Foundation of Hubei Province (2019CFB432)
- National Natural Science Foundation of China (21976063, 22076052)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Chemistry › Organic Chemistry › Sulfur-Based Synthesis Techniques
- Keywords
- peroxymonosulfate, advanced oxidation processes, p-cresol, phenol degradation, carbonate radical, singlet oxygen, electron transfer, Hammett substituent constants, substituent electronic effects, catalyst stability, copper reduction, degradation kinetics
- MeSH terms
- Carbonates, Peroxides, Phenols, Water Pollutants, Chemical
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- CoChat. (2026). Citation check: Carbonate-induced enhancement of phenols degradation in CuS/peroxymonosulfate system: A clear correlation between this enhancement and electronic effects of phenols substituents. https://app.cochat.ai/papers/10.1016/j.jes.2022.09.018
- The paper
- Wang, X., Zhou, Y., Wang, N., Zhang, J., & Zhu, L. (2023). Carbonate-induced enhancement of phenols degradation in CuS/peroxymonosulfate system: A clear correlation between this enhancement and electronic effects of phenols substituents. Journal of Environmental Sciences. https://doi.org/10.1016/j.jes.2022.09.018
