The DOI matches its Crossref record; 161 of the 161 references it cites were found in a registry or an index.
Uncertainty and misinterpretation over identification, quantification and transformation of reactive species generated in catalytic oxidation processes: A review
Abstract
The identification of reactive radical species using quenching and electron paramagnetic resonance (EPR) tests has attracted extensive attention, but some mistakes or misinterpretations are often present in recent literature. This review aims to clarify the corresponding issues through surveying literature, including the uncertainty about the identity of radicals in the bulk solution or adsorbed on the catalyst surface in quenching tests, selection of proper scavengers, data explanation for incomplete inhibition, the inconsistent results between quenching and EPR tests (e.g., SO4•- is predominant in quenching test while the signal of •OH predominates in EPR test), and the incorrect identification of EPR signals (e.g., SO4•- is identified by indiscernible or incorrect signals). In addition, this review outlines the transformation of radicals for better tracing the origin of radicals. It is anticipated that this review can help in avoiding mistakes while investigating catalytic oxidative mechanism with quenching and EPR tests.
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Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks
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Cited by
Xie, Z.-H., He, C.-S., Pei, D.-N., Dong, Y., Yang, S.-R., Xiong, Z., Zhou, P., Pan, Z.-C., Yao, G., & Lai, B. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.143778 · Cited by 279
Metadata
- Authors
- Wang, L., Lan, X., Peng, W., & Wang, Z.
- Venue
- Journal of Hazardous Materials
- Publisher
- Elsevier BV
- Published
- 2021-04
- Volume
- 408
- Pages
- 124436
- ISSN
- 0304-3894 (ISSN-L)
- OpenAlex
- W3097894213
- Cited by
- 689
- References
- 161
- FWCI
- 20.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, L., Lan, X., Peng, W., & Wang, Z. (2021). Uncertainty and misinterpretation over identification, quantification and transformation of reactive species generated in catalytic oxidation processes: A review. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2020.124436
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
